Infrared electronic absorption in a single-component molecular metal

被引：45

作者：

Kobayashi, A

Sasa, M

Suzuki, W

Fujiwara, E

Tanaka, H

Tokumoto, M

Okano, Y

Fujiwara, H

Kobayashi, H ^{[1
]}

机构：

[1] JST, Inst Mol Sci, Okazaki, Aichi 4448585, Japan

[2] CREST, Okazaki, Aichi 4448585, Japan

[3] Univ Tokyo, Res Ctr Spectrochem, Grad Sch Sci, Bunkyo Ku, Tokyo 1130033, Japan

[4] AIST, Nanotechnol Res Inst, Tsukuba, Ibaraki 3058568, Japan

[5] JST, CREST, Tsukuba, Ibaraki 3058568, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 02期

关键词：

D O I：

10.1021/ja0379767

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The infrared spectra of the crystal of transition metal complex molecules with extended-TTF ligands, Ni(tmdt)2, which is the first single-component molecular metal that has a stable metallic state even at low temperatures, exhibited an extremely low-energy electronic absorption around 2200 cm-1 (tmdt = trimethylenetetrathiafulvalenedithiolate). The systematic shift of the absorption peaks for molecules similar to Ni(tmdt)2, which range from metallic to semiconducting crystals, shows that the single-component molecular conductors are composed of molecules with unprecedentedly small HOMO-LUMO gaps. Copyright © 2004 American Chemical Society.

引用

页码：426 / 427

页数：2

共 16 条

[1] Preparation and chemistry of new unsymmetrically substituted tetrachalcogenofulvalenes bearing CN(CH2)(2)X and HO(CH2)(2)X groups (X=S or Se) [J].