Generation and characterization of high-valent iron oxo phthalocyanines

被引：62

作者：

Afanasiev, Pavel ^{[1
]}

Kudrik, Evgeny V. ^{[1
,2
]}

Albrieux, Florian ^{[3
]}

Briois, Valerie ^{[4
]}

Koifman, Oskar I. ^{[2
]}

Sorokin, Alexander B. ^{[1
]}

机构：

[1] Univ Lyon, CNRS, UMR 5256, Inst Rech Catalyse & Environm Lyon IRCELYON, F-69626 Villeurbanne, France

[2] Ivanovo State Univ Chem & Technol, Inst Macroheterocycl Cpds, Ivanovo 153000, Russia

[3] Univ Lyon 1, UMR 5246, Ctr Commun Spectrometrie Masse, F-69622 Villeurbanne, France

[4] Synchrotron Soleil, Lorme Merisiers, F-91192 Gif Sur Yvette, France

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 49期

关键词：

DENSITY-FUNCTIONAL THEORY; X-RAY SPECTROSCOPY; OXYGENATION REACTIONS; METAL-COMPLEXES; K-EDGE; C-H; OXIDATION; CYTOCHROME-P450; INTERMEDIATE; ACTIVATION;

D O I：

10.1039/c2cc31917a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first high-valent iron oxo complex on the phthalocyanine platform has been prepared from iron tetra-tert-butyl-phthalocyanine and m-chloroperbenzoic acid and characterized by low temperature UV-vis, cryospray MS, EPR, X-ray absorption and high resolution X-ray emission methods.

引用

页码：6088 / 6090

页数：3

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