Co/SiO2 catalysts prepared from CO2(CO)8 for CO hydrogenation into alcohols and hydrocarbons:: characterization by magnetic methods and temperature-programmed hydrogenation

The hydrogenation of carbon monoxide over Co/SiO2 catalysts obtained by reduction of precursors prepared by the reaction of dicobaltoctacarbonyl with silica gives rise to a mixture of alcohols and hydrocarbons. The chain growth probability a! for hydrocarbon synthesis is similar to that observed over conventional catalysts prepared by the ammonia method (alpha = 0.74) with a comparable metal dispersion (metal particle size 4 nm). Alcohol formation yields a smaller chain growth probability (alpha = 0.42). Magnetic measurements have shown that in the latter catalyst, small cobalt clusters (similar to1 nm) are likely to be present together with the cobalt particles (4 nm), this observation reconciles apparently conflicting results from the literature. It has been speculated that alcohol formation might be related to the presence of these clusters according to a concerted mechanism. Furthermore, the observation of large amounts of acetates by temperature-programmed hydrogenation, not detected in hydrocarbon selective catalysts, suggests that they may play a role in ethanol synthesis. (C) 2001 Elsevier Science B.V. All rights reserved.