An unusual addition-rearrangement of a dialkoxycarbene to C-60: Exclusion of methanofullerene products

被引：26

作者：

Gonzalez, R

Wudl, F

Pole, DL

Sharma, PK

Warkentin, J

机构：

[1] UNIV CALIF SANTA BARBARA,INST POLYMERS & ORGAN SOLIDS,SANTA BARBARA,CA 93106

[2] UNIV CALIF SANTA BARBARA,DEPT CHEM,SANTA BARBARA,CA 93106

[3] MCMASTER UNIV,HAMILTON,ON L8S 4M1,CANADA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1996年 / 61卷 / 17期

关键词：

D O I：

10.1021/jo9603136

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The expected (dialkoxymethano)fullerene 3, which would be generated by the addition of methoxy-[2-(trimethylsilyl)ethoxy]carbene across a carbon-carbon double bond of C-60, was not obtained; the 1,2- and 1,4-dihydrofullerenes 1 and 2 were isolated instead. The novel compounds 1 and 2 were characterized by C-13- and H-1-NMR as well as FTIR and UV-vis spectroscopies. A mechanism for their formation is suggested.

引用

页码：5837 / 5839

页数：3

共 17 条

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