Synthesis and characterization of SnO-carbon nanotube composite as anode material for lithium-ion batteries

被引:86
作者
Chen, MH [1 ]
Huang, ZC [1 ]
Wu, GT [1 ]
Zhu, GM [1 ]
You, JK [1 ]
Lin, ZG [1 ]
机构
[1] Xiamen Univ, Dept Chem, State Key Lab Phys Chem Solid Surface, Xiamen 361005, Fujian, Peoples R China
关键词
composite; electrochemical properties;
D O I
10.1016/S0025-5408(03)00063-1
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
SnO-carbon nanotube composite was synthesized by a sol-gel method. The electrochemical behavior of the composite using an anode active material in lithium-ion batteries was investigated. It was found that the composite showed enhanced anode performance compared with the unsupported SnO or carbon nanotube (CNT). The capacity fade of the composite electrode was reduced over unsupported SnO or CNT. We attribute the results to the conductivity and ductility of the CNT matrix, and the high dispersion of SnO. (C) 2003 Published by Elsevier Science Ltd.
引用
收藏
页码:831 / 836
页数:6
相关论文
共 15 条
  • [1] Carbon nanotubule membranes for electrochemical energy storage and production
    Che, GL
    Lakshmi, BB
    Fisher, ER
    Martin, CR
    [J]. NATURE, 1998, 393 (6683) : 346 - 349
  • [2] Lithium alloy negative electrodes formed from convertible oxides
    Huggins, RA
    [J]. SOLID STATE IONICS, 1998, 113 : 57 - 67
  • [3] Tin-based amorphous oxide: A high-capacity lithium-ion-storage material
    Idota, Y
    Kubota, T
    Matsufuji, A
    Maekawa, Y
    Miyasaka, T
    [J]. SCIENCE, 1997, 276 (5317) : 1395 - 1397
  • [4] Idota Y., 1995, Eur. Patent, P1, Patent No. [0651450A1, 0651450]
  • [5] Lithium intercalation and deintercalation reactions in synthetic graphite containing a high dispersion of SnO
    Lee, JY
    Zhang, RF
    Liu, ZL
    [J]. ELECTROCHEMICAL AND SOLID STATE LETTERS, 2000, 3 (04) : 167 - 170
  • [6] Dispersion of Sn and SnO on carbon anodes
    Lee, JY
    Zhang, RF
    Liu, ZL
    [J]. JOURNAL OF POWER SOURCES, 2000, 90 (01) : 70 - 75
  • [7] Effect of working pressure on the electrochemical performance of thin film SnO2 microbattery anodes deposited by radio frequency magnetron sputtering
    Lee, WH
    Son, HC
    Reucroft, PJ
    Lee, JG
    Park, JW
    [J]. JOURNAL OF MATERIALS SCIENCE LETTERS, 2001, 20 (01) : 39 - 41
  • [8] A high capacity nano-Si composite anode material for lithium rechargeable batteries
    Li, H
    Huang, XJ
    Chen, LQ
    Wu, ZG
    Liang, Y
    [J]. ELECTROCHEMICAL AND SOLID STATE LETTERS, 1999, 2 (11) : 547 - 549
  • [9] Structure and electrochemical properties of anodes consisting of modified SnO
    Li, H
    Huang, XJ
    Chen, LQ
    [J]. JOURNAL OF POWER SOURCES, 1999, 81 : 335 - 339
  • [10] Li NC, 2000, ELECTROCHEM SOLID ST, V3, P316, DOI 10.1149/1.1391134