Hydrogen storage using polymer-supported organometallic dihydrogen complexes: a mechanistic study

被引：14

作者：

Cooper, Andrew I.

Poliakoff, Martyn

机构：

[1] Univ Liverpool, Dept Chem, Liverpool, Merseyside, England

[2] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England

来源：

CHEMICAL COMMUNICATIONS | 2007年 / 28期

关键词：

D O I：

10.1039/b703701e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The dihydrogen complex W(CO)(5)(H-2) can be both generated and dissociated in polymer matrices by UV photolysis at 220 K and 90 K, respectively, suggesting a potential "UV-activated'' mechanism for hydrogen storage and release.

引用

页码：2965 / 2967

页数：3

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