Synthesis, reaction chemistry and electrochemical behaviour of (η5-C5H4SiMe3)2Hf(CCFc)2

被引：26

作者：

Back, S

Rheinwald, G

Zsolnai, L

Huttner, G

Lang, H

机构：

[1] Tech Univ Chemnitz, Inst Chem, Lehrstuhl Anorgan Chem, D-09111 Chemnitz, Germany

[2] Univ Heidelberg, Inst Anorgan Chem, D-69120 Heidelberg, Germany

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1998年 / 563卷 / 1-2期

关键词：

hafnocene; ferrocene; alkyne; nickelcarbonyl;

D O I：

10.1016/S0022-328X(98)00556-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[Hf]Cl-2 (1) {[Hf] = (eta(5)-C5H4SiMe3)(2)Hf} reacts with 2.0 mol equiv of LiC=CFc (2) [Fc=(eta(5)-C5H4)(eta(5)-C5H5)Fe] to produce [Hf](C=CFc)(2) (3). Treatment of 3 with Ni(CO)(4); (4) affords {[Hf](C=CFc)(2)}Ni(CO) (5). The electrochemical behaviour of 3 is discussed. The X-ray structure analysis of 3 is reported; 3 crystallizes in the orthorhombic space group Pnna with cell constants a = 11.431(2), b = 16.521(2), c = 19.130(2) Angstrom V, = 3612.7(9) Angstrom(3); and Z = 4. (C) 1998 Elsevier Science S.A. All rights reserved.

引用

收藏

页码：73 / 79

页数：7

相关论文

共 101 条

[1] SYNTHESIS OF FERROCENYLACETYLENES [J].

ABRAM, TS ;

WATTS, WE .

SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1976, 6 (01) :31-53

[2]

[Anonymous], ANGEW CHEM

[3] SILYLMETHYL AND RELATED COMPLEXES .5. METALLOCENE BIS(TRIMETHYLSILYL)METHYLS AND BENZHYDRYLS OF EARLY TRANSITION-METALS [M(ETA5-C5H5)2R](M = TI OR V) AND [META5-C5H5)2(X)R](M = ZR OR HF AND X = CL OR R), AND CRYSTAL AND MOLECULAR STRUCTURES OF [M(ETA5-C5H5)2(CHPH2)2] (M = ZR OR HF) [J].

ATWOOD, JL ;

BARKER, GK ;

HOLTON, J ;

HUNTER, WE ;

LAPPERT, MF ;

PEARCE, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1977, 99 (20) :6645-6652

[4] C2-bridged titanocene-ferrocenyl complexes:: Synthesis, reaction chemistry, and electrochemical behavior [J].

Back, S ;

Pritzkow, H ;

Lang, H .

ORGANOMETALLICS, 1998, 17 (01) :41-44

[5] BIS(ETA-5-CYCLOPENTADIENYL)HAFNIUM COMPLEXES CONTAINING SIGMA-BONDED ALKYNYL GROUPS [J].

BARRAL, MC ;

JIMENEZ, R ;

SANTOS, A .

INORGANICA CHIMICA ACTA-ARTICLES, 1982, 63 (02) :257-260

[6]

BARTIK T, 1996, ANGEW CHEM INT EDIT, V35, P968

[7] METHODS FOR THE SYNTHESIS OF MU-HYDROCARBON TRANSITION-METAL COMPLEXES WITHOUT METAL-METAL BONDS [J].

BECK, W ;

NIEMER, B ;

WIESER, M .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1993, 32 (07) :923-949

[8] NEW BIMETALLIC HYDROCARBON-BRIDGED COMPLEXES BY NUCLEOPHILIC-ATTACK OF CARBONYLMETALLATES TO COORDINATED UNSATURATED-HYDROCARBONS [J].

BECK, W ;

NIEMER, B ;

BREIMAIR, J ;

HEIDRICH, J .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 372 (01) :79-83

[9]

BECK W, 1993, ANGEW CHEM, V105, P969

[10] ALPHA-HALOFERROCENES - SYNTHESIS OF FERROCENYLACETYLENE [J].

BENKESER, RA ;

FITZGERALD, WP .

JOURNAL OF ORGANIC CHEMISTRY, 1961, 26 (10) :4179-&

← 1 2 3 4 5 6 7 8 9 10 →