High-throughput automated parallel evaluation of zinc-based catalysts for the copolymerization of CHO and CO2 to polycarbonates

被引：24

作者：

van Meerendonk, WJ

Duchateau, R

Koning, CE

Gruter, GJM

机构：

[1] Avantium Technol, NL-1014 BV Amsterdam, Netherlands

[2] Eindhoven Univ Technol, Polymer Chem Lab, NL-5600 MB Eindhoven, Netherlands

[3] Dutch Polymer Inst, NL-5600 MB Eindhoven, Netherlands

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 2004年 / 25卷 / 01期

关键词：

carbon dioxide; catalysis; copolymerization; high-throughput experimentation; parallel synthesis;

D O I：

10.1002/marc.200300255

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Copolymerization of CO2 and oxiranes using high-pressure autoclaves typically allows one experiment per reactor per day. As a high-throughput approach for this chemistry would be extremely valuable, a parallel setup has been validated for the copolymerization of CO2 and cyclohexene oxide (CHO) with two beta-diiminato zinc complexes. Molecular weights, polydispersities and activities were found to be comparable with literature values.

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页码：382 / 386

页数：5

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