Porous membrane controlled polymerization of nanofibers of polyaniline and its derivatives

被引:21
作者
Chiou, Nan-Rong [1 ,2 ,3 ]
Lee, L. James [1 ]
Epstein, Arthur J. [1 ,4 ]
机构
[1] Ohio State Univ, Dept Chem & Biomol Engn, Columbus, OH 43210 USA
[2] Ohio State Univ, Dept Phys, Columbus, OH 43210 USA
[3] Nanomat Innovat Ltd, Columbus, OH 43212 USA
[4] Ohio State Univ, Dept Chem, Columbus, OH 43210 USA
关键词
D O I
10.1039/b719320c
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 [物理化学]; 081704 [应用化学];
摘要
A novel, simple, and scalable technique to control the formation of the nanofibers of polyaniline and its derivatives via porous membrane controlled polymerization (PMCP) is reported. Through appropriate synthesis conditions, there are nearly 100% nanofibers formed with diameters tunable from 20nm to 250nm via the selection of pore diameter, monomer, counterions, and polymerization conditions. The nanofiber lengths vary from sub-micrometre to several micrometres. A single nanofiber can be easily isolated from the agglomeration. X-Ray diffraction patterns show that doped polyaniline nanofibers are substantially crystalline.
引用
收藏
页码:2085 / 2089
页数:5
相关论文
共 25 条
[1]
A simple approach to control the growth of polyaniline nanofibers [J].
Chiou, NR ;
Epstein, AJ .
SYNTHETIC METALS, 2005, 153 (1-3) :69-72
[2]
Polyaniline nanofibers prepared by dilute polymerization [J].
Chiou, NR ;
Epstein, AJ .
ADVANCED MATERIALS, 2005, 17 (13) :1679-+
[3]
Epstein AJ, 1992, US Patent, Patent No. 5135696
[4]
Nanofiber formation in the chemical polymerization of aniline: A mechanistic study [J].
Huang, JX ;
Kaner, RB .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (43) :5817-5821
[5]
A general chemical route to polyaniline nanofibers [J].
Huang, JX ;
Kaner, RB .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (03) :851-855
[6]
The intrinsic nanofibrillar morphology of polyaniline [J].
Huang, JX ;
Kaner, RB .
CHEMICAL COMMUNICATIONS, 2006, (04) :367-376
[7]
POLYANILINE, A NOVEL CONDUCTING POLYMER - MORPHOLOGY AND CHEMISTRY OF ITS OXIDATION AND REDUCTION IN AQUEOUS-ELECTROLYTES [J].
HUANG, WS ;
HUMPHREY, BD ;
MACDIARMID, AG .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1986, 82 :2385-&
[8]
Oligomer-assisted synthesis of chiral polyaniline nanofibers [J].
Li, WG ;
Wang, HL .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (08) :2278-2279
[9]
Electronic transport in single polyaniline and polypyrrole microtubes [J].
Long, YZ ;
Zhang, LJ ;
Chen, ZJ ;
Huang, K ;
Yang, YS ;
Xiao, HM ;
Wan, MX ;
Jin, AZ ;
Gu, CZ .
PHYSICAL REVIEW B, 2005, 71 (16)
[10]
MacDiarmid A. G., 1987, Conducting Polymers. Special Applications. Proceedings of the Workshop, P105