Novel intramolecular hydrogen-atom transfer in an eta(4)-ligated cycloocta-1,5-diene eta-1,2,4-triphosphole ruthenium(0) complex. Synthesis, crystal and molecular structures of [RU(eta(4)-C8H12){eta-P(3)C(2)Bu(2)(t)[CH(SiMe(3))(2)]}] and [Ru(eta(5)-C8H11){eta-P(3)C(2)Bu(2)(t)H[CH(SiMe(3))2]}]

被引：14

作者：

Hitchcock, PB ^{[1
]}

Nixon, JF ^{[1
]}

Sakarya, N ^{[1
]}

机构：

[1] UNIV SUSSEX,SCH CHEM PHYS & ENVIRONM SCI,BRIGHTON BN1 9QJ,E SUSSEX,ENGLAND

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 24期

关键词：

D O I：

10.1039/cc9960002751

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first known ruthenium(0) complex of a 1,2,4-triphosphole is reported which undergoes a novel hydrogen migration reaction from the eta 4-cycloocta-1,5-diene coligand on heating.

引用

页码：2751 / 2752

页数：2

共 11 条

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