A simple solution-phase reduction method for the synthesis of shape-controlled platinum nanoparticles

被引:42
作者
Tang, ZC [1 ]
Geng, DS [1 ]
Lu, GX [1 ]
机构
[1] Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China
关键词
platinum nanoparticles; solution-phase reduction method; fine structure; nanomaterials; crystal structure;
D O I
10.1016/j.matlet.2005.01.024
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Using poly-vinylpyrrolidone (PVP) as capping agent, snowlike platinum nanoparticles, for the first time, were synthesized by reducing H2PtCl6 with hydrogen. Pt nanoparticles were characterized by powder X-ray diffraction (XRD), transmission electron microscopy (TEM), and UV-Vis absorption spectrum. With increasing or decreasing the quantity of H2PtCl6, the product's structure changes from snowlike structures to triangular. The diffusion-limited aggregate model can be used to explain the growth of snowlike platinum nanoparticles. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:1567 / 1570
页数:4
相关论文
共 14 条
[1]   Shape-controlled synthesis of colloidal platinum nanoparticles [J].
Ahmadi, TS ;
Wang, ZL ;
Green, TC ;
Henglein, A ;
ElSayed, MA .
SCIENCE, 1996, 272 (5270) :1924-1926
[2]  
BUYANOV RA, 1983, COK FORMATION CATALY, P207
[3]   Shape-selective preparation and properties of oxalate-stabilized Pt colloid [J].
Fu, XY ;
Wang, YA ;
Wu, NZ ;
Gui, LL ;
Tang, YQ .
LANGMUIR, 2002, 18 (12) :4619-4624
[4]   Electrocatalysis of methanol oxidation [J].
Iwasita, T .
ELECTROCHIMICA ACTA, 2002, 47 (22-23) :3663-3674
[5]   Chirality of large random supramolecular structures [J].
Katzenelson, O ;
HelOr, HZ ;
Avnir, D .
CHEMISTRY-A EUROPEAN JOURNAL, 1996, 2 (02) :174-181
[6]   Biomolecule-assisted synthesis of highly ordered snowflakelike structures of bismuth sulfide nanorods [J].
Lu, QY ;
Gao, F ;
Komarneni, S .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (01) :54-55
[7]   Ultrahigh-density nanowire lattices and circuits [J].
Melosh, NA ;
Boukai, A ;
Diana, F ;
Gerardot, B ;
Badolato, A ;
Petroff, PM ;
Heath, JR .
SCIENCE, 2003, 300 (5616) :112-115
[8]   Controlled synthesis of 2-D and 3-D dendritic platinum nanostructures [J].
Song, YJ ;
Yang, Y ;
Medforth, CJ ;
Pereira, E ;
Singh, AK ;
Xu, HF ;
Jiang, YB ;
Brinker, CJ ;
van Swol, F ;
Shelnutt, JA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (02) :635-645
[9]   High dispersion and electrocatalytic properties of platinum nanoparticles on graphitic carbon nanofibers (GCNFs) [J].
Tang, H ;
Chen, JH ;
Nie, LH ;
Liu, DY ;
Deng, W ;
Kuang, YF ;
Yao, SZ .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2004, 269 (01) :26-31
[10]   Low-temperature CO oxidation over platinum and cobalt oxide catalysts [J].
Thormählen, P ;
Skoglundh, M ;
Fridell, E ;
Andersson, B .
JOURNAL OF CATALYSIS, 1999, 188 (02) :300-310