Liquid Catholyte Molecules for Nonaqueous Redox Flow Batteries

被引：159

作者：

Huang, Jinhua ^{[1
]}

Cheng, Lei ^{[2
]}

Assary, Rajeev S. ^{[2
]}

Wang, Peiqi ^{[1
]}

Xue, Zheng ^{[1
]}

Burrell, Anthony K. ^{[1
]}

Curtiss, Larry A. ^{[2
]}

Zhang, Lu ^{[1
]}

机构：

[1] Chem Sci & Engn Div, Argonne, IL 60439 USA

[2] Argonne Natl Lab, Div Mat Sci, Argonne, IL 60439 USA

来源：

ADVANCED ENERGY MATERIALS | 2015年 / 5卷 / 06期

关键词：

catholytes; electrochemistry; nonaqueous redox flow batteries; redox-active molecules; rational molecular design; ION; ELECTROLYTES; OVERCHARGE; SHUTTLE; PROTECTION; DIFFUSION; PROGRESS; CELL;

D O I：

10.1002/aenm.201401782

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070305 [高分子化学与物理];

摘要：

A series of dimethoxybenzene-based catholyte molecules, which are electrochemically reversible at high potential (4.0 V vs Li/Li+) and in the form of liquid, is developed. The liquid nature offers the molecules the possibility of being a solo or co-solvent for nonaqueous redox flow batteries. This could dramatically improve the energy density. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

收藏

页数：6

相关论文

共 30 条

[1]

Li+-(diglyme)2 and LiClO4-diglyme complexes:: Barriers to lithium ion migration [J].

Baboul, AG ;

Redfern, PC ;

Sutjianto, A ;

Curtiss, LA .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (31) :7220-7227

[2]

An All-Organic Non-aqueous Lithium-Ion Redox Flow Battery [J].

Brushett, Fikile R. ;

Vaughey, John T. ;

Jansen, Andrew N. .

ADVANCED ENERGY MATERIALS, 2012, 2 (11) :1390-1396

[3]

Burgstahler A. W., 1966, ORGANIC SYNTHESIS

[4]

Evaluation of electrolytes for redox flow battery applications [J].

Chakrabarti, M. H. ;

Dryfe, R. A. W. ;

Roberts, E. P. L. .

ELECTROCHIMICA ACTA, 2007, 52 (05) :2189-2195

[5]

Chemical overcharge and overdischarge protection for lithium-ion batteries [J].

Chen, J ;

Buhrmester, C ;

Dahn, JR .

ELECTROCHEMICAL AND SOLID STATE LETTERS, 2005, 8 (01) :A59-A62

[6]

Pathways to low-cost electrochemical energy storage: a comparison of aqueous and nonaqueous flow batteries [J].

Darling, Robert M. ;

Gallagher, Kevin G. ;

Kowalski, Jeffrey A. ;

Ha, Seungbum ;

Brushett, Fikile R. .

ENERGY & ENVIRONMENTAL SCIENCE, 2014, 7 (11) :3459-3477

[7]

Redox flow cells for energy conversion [J].

de Leon, C. Ponce ;

Frias-Ferrer, A. ;

Gonzalez-Garcia, J. ;

Szanto, D. A. ;

Walsh, F. C. .

JOURNAL OF POWER SOURCES, 2006, 160 (01) :716-732

[8]

A metal-free organic-inorganic aqueous flow battery [J].

Huskinson, Brian ;

Marshak, Michael P. ;

Suh, Changwon ;

Er, Sueleyman ;

Gerhardt, Michael R. ;

Galvin, Cooper J. ;

Chen, Xudong ;

Aspuru-Guzik, Alan ;

Gordon, Roy G. ;

Aziz, Michael J. .

NATURE, 2014, 505 (7482) :195-+

[9]

Jansen A. N., 2013, U. S. Patent Application, Patent No. 20130224538

[10]

Measurement of Solution Viscosity via Diffusion-Ordered NMR Spectroscopy (DOSY) [J].

Li, Weibin ;

Kagan, Gerald ;

Hopson, Russell ;

Williard, Paul G. .

JOURNAL OF CHEMICAL EDUCATION, 2011, 88 (09) :1331-1335