Atom Transfer Radical Polymerization: A Robust and Versatile Route for Polymer Synthesis

被引：62

作者：

Ayres, Neil ^{[1
]}

机构：

[1] Univ Cincinnati, Dept Chem, Cincinnati, OH 45221 USA

来源：

POLYMER REVIEWS | 2011年 / 51卷 / 02期

关键词：

CHAIN-END FUNCTIONALITY; HYBRID CATALYST SYSTEM; NITROGEN-BASED LIGANDS; REVERSE ATRP PROCESS; METHYL-METHACRYLATE; ELECTRON-TRANSFER; SET-LRP; ARGET ATRP; IRON CATALYSTS; AGET ATRP;

D O I：

10.1080/15583724.2011.566402

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Atom transfer radical polymerization (ATRP) has become an established synthetic methodology to prepare polymers of high molecular weights with narrow molecular weight distributions and living polymerization characteristics. This review is a conceptual overview of ATRP and the components of an ATRP system. Current approaches to reduce the transition metal concentration are then described including activators regenerated by electron transfer (ARGET) ATRP. Finally, a recent polymerization approach, single electron transfer living radical polymerization (SET-LRP), is described.

引用

收藏

页码：138 / 162

页数：25

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