Non-Langevin bimolecular recombination in a silole-based polymer:PCBM solar cell measured by time-resolved charge extraction and resistance-dependent time-of-flight techniques

被引：36

作者：

Clarke, Tracey M. ^{[1
]}

Peet, Jeff ^{[2
]}

Denk, Patrick ^{[3
]}

Dennler, Gilles ^{[2
,4
]}

Lungenschmied, Christoph ^{[2
]}

Mozer, Attila J. ^{[1
]}

机构：

[1] Univ Wollongong, ARC Ctr Excellence Electromat Sci, Intelligent Polymer Res Inst, N Wollongong, NSW 2500, Australia

[2] Konarka Technol, Lowell, MA 01852 USA

[3] Konarka Austria, A-4040 Linz, Austria

[4] IMRA Europe, F-06904 Sophia Antipolis, France

来源：

ENERGY & ENVIRONMENTAL SCIENCE | 2012年 / 5卷 / 01期

基金：

澳大利亚研究理事会;

关键词：

BLENDS;

D O I：

10.1039/c1ee02434e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The silole-based non-Langevin conjugated polymer KP115 has been used to demonstrate that circuit resistance is a crucial parameter in time-of-flight measurements of organic photovoltaic cells, providing a resistance-dependent bimolecular recombination coefficient. The origin of this behaviour is the biphasic decay dynamics present in KP115:PCBM devices (observed using a novel time-dependent charge extraction technique), which time-of-flight cannot accurately characterise.

引用

页码：5241 / 5245

页数：5

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