Ion conducting behaviour of polymer electrolytes containing ionic liquids

被引:68
作者
Singh, B [1 ]
Sekhon, SS [1 ]
机构
[1] Guru Nanak Dev Univ, Dept Appl Phys, Amritsar 143005, Punjab, India
关键词
D O I
10.1016/j.cplett.2005.08.046
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Ionic liquids containing 2,3-dimethyl-1-octylimidazolium (DMOIm(+)) cation and BF4-, PF6-, CF3SO3-, N(CF3SO2)(2)(-) anions have been synthesized and incorporated in different polymers to obtain polymer electrolytes which show conductivity over a wide range (10(-3)-10(-6) S/cm). Polymer electrolytes containing polyvinylideneflouride-hexafluoropropylene (PVdF-HFP)in DMOImCF(3)SO(3) show maximum conductivity in the 20-120 degrees C temperature range which is only an order of magnitude lower than for the neat ionic liquid (10(-2) S/cm). (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:34 / 39
页数:6
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