Iron(II) spin transition 1,2,4-triazole chain compounds with novel inorganic fluorinated counteranions

被引：26

作者：

Dirtu, Marinela M.

Garcia, Yann

Nica, Mihai

Rotarii, Aurelian

Linares, Jorge

Varret, Francois

机构：

[1] Univ Catholique Louvain, Dept Chim, Unite Chim Mat Inrogan & Organ, B-1348 Louvain, Belgium

[2] Univ Versailles St Quentin Yvelines, Grp Etud Matiere Condensee, F-78035 Versailles, France

[3] Alexandru Ioan Cuza Univ, Dept Solid State & Theoret Phys, Iasi, Romania

来源：

POLYHEDRON | 2007年 / 26卷 / 9-11期

关键词：

spin transition; 1 ',2,4-triazole; Mossbauer; iron(II); bistability;

D O I：

10.1016/j.poly.2006.11.009

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New one-dimensional spin transition coordination polymers of formula [Fe(NH(2)trZ)(3)](AF(6)) center dot nH(2)O (A = Ti, Zr, Sn; NH(2)trz = 4-amino-1,2,4-triazole) have been synthesized in MeOH and EtOH media. These materials display an abrupt and hysteretic spin transition around 200 K as well as a reversible thermochromic effect on, cooling. A preliminary evaluation of the lattice dynamics in the high-spin and low-spin states is presented. (c) 2006 Elsevier Ltd. All rights reserved.

引用

页码：2259 / 2263

页数：5

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