Recent advances in metal phosphonate chemistry II

被引：220

作者：

Clearfield, A ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA

来源：

CURRENT OPINION IN SOLID STATE & MATERIALS SCIENCE | 2002年 / 6卷 / 06期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S1359-0286(02)00151-1

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Phosphonic acids are more acidic than carboxylic acids. They are non-planar and possess twice the number of protons. These attributes lead to strong hydrogen bond formation that can be utilized in design of crystal-engineered structures and self-assembled supramolecular arrays. Their superior cation complexing ability leads to formation of a vast number of metal complexes and their use in lanthanide and actinide separations. Recent work, largely drawn from the work of the author's research group, is summarized in this update of the author's 1996 review [Cuff Opin Solid State Mater Sci 1 (1996) 268]. (C) 2003 Elsevier Science Ltd. All rights reserved.

引用

页码：495 / 506

页数：12

共 24 条

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