Preparation, characterization, and theoretical studies of azelaic acid derived from oleic acid by use of a novel ozonolysis method

被引：21

作者：

Kadhum, Abdul Amir H. ^{[1
]}

Wasmi, Bilal A. ^{[1
]}

Mohamad, Abu Bakar ^{[1
]}

Al-Amiery, Ahmed A. ^{[1
,2
]}

Takriff, Mohd S. ^{[1
]}

机构：

[1] Univ Kebangsaan Malaysia, Fac Engn & Built Environm, Dept Chem & Proc Engn, Bangi 43600, Malaysia

[2] Univ Technol Baghdad, Dept Appl Sci, Div Biotechnol, Baghdad 10066, Iraq

来源：

RESEARCH ON CHEMICAL INTERMEDIATES | 2012年 / 38卷 / 02期

关键词：

Azelaic acid; Bubbling; Dicarboxylic acids; NMR spectrum; Theoretical study; CONVERSION;

D O I：

10.1007/s11164-011-0406-8

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Environmentally friendly manufacture of organic compounds has been intensively reexamined in recent years. Many excellent methods have been devised to produce organic compounds from renewable resources. Azelaic acid has been produced by ozonolysis of oleic acid. The reaction was performed in a Bach bubbling reactor, with fine bubbles, at high temperature (150 A degrees C) without utilizing any catalyst or any solvent. Yield of the reaction was 20% after 2 h. Production of azelaic acid was confirmed by use of FT-IR and H-1 NMR spectroscopic data and high-performance liquid chromatography of both synthesized and reference azelaic acid. A theoretical study was performed to obtain quantum chemical data for azelaic acid and to optimize the molecule's geometry.

引用

页码：659 / 668

页数：10

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