CO2 coordination by inorganic polyoxoanion in water

被引:108
作者
Gao, Guanggang [1 ]
Li, Fengyan [1 ]
Xu, Lin [1 ]
Liu, Xizheng [1 ]
Yang, Yanyan [1 ]
机构
[1] NE Normal Univ, Dept Chem, Key Lab Polyoxometalate Sci Minist Educ, Changchun 130024, Jilin, Peoples R China
基金
中国国家自然科学基金;
关键词
D O I
10.1021/ja801560t
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Two inorganic polyoxoanions react with carbon dioxide in aqueous solution to yield two polymeric chainlike complexes, where an activated CO2 molecule covalently bonds to polyoxoanions in a linear mu-eta(1),eta(1)-OCO style. For the first time, the CO2 coordination is realized by an economic and environmentally friendly approach.
引用
收藏
页码:10838 / +
页数:3
相关论文
共 23 条
[1]  
Baines S.J., 2004, Geological Storage of Carbon Dioxide, V233, P1
[2]   Spatially resolved Raman and UV-visible-NIR spectroscopy on the preparation of supported catalyst bodies:: Controlling the formation of H2PMo11CoO405- inside Al2O3 pellets during impregnation [J].
Bergwerff, JA ;
van de Water, LGA ;
Visser, T ;
de Peinder, P ;
Leliveld, BRG ;
de Jong, KP ;
Weckhuysen, BM .
CHEMISTRY-A EUROPEAN JOURNAL, 2005, 11 (16) :4592-4601
[3]   Topological redox isomers: Surface chemistry of zeolite-encapsulated Co(salen) and [Fe(bpy)(3)](2+) complexes [J].
Bessel, CA ;
Rolison, DR .
JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (07) :1148-1157
[4]   Carbon dioxide reduction and carbon monoxide activation employing a reactive uranium(III) complex [J].
Castro-Rodriguez, I ;
Meyer, K .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (32) :11242-11243
[5]   A linear, O-coordinated η1-CO2 bound to uranium [J].
Castro-Rodriguez, I ;
Nakai, H ;
Zakharov, LN ;
Rheingold, AL ;
Meyer, K .
SCIENCE, 2004, 305 (5691) :1757-1759
[6]   STABILIZATION OF THE DEFECT (LACUNARY) COMPLEX PMO11O39(7-) - ISOLATION, PURIFICATION, STABILITY CHARACTERISTICS, AND METALATION CHEMISTRY [J].
COMBSWALKER, LA ;
HILL, CL .
INORGANIC CHEMISTRY, 1991, 30 (21) :4016-4026
[7]   Novel carbon dioxide and carbonyl carbonate complexes of molybdenum.: The X-ray structures of trans-[Mo(CO2)2{HN(CH2CH2PMe2)2}(PMe3)] and [Mo3(μ2-CO3)(μ2-O)2(O)2(CO)2(H2O)(PMe3)6]•H2O [J].
Contreras, L ;
Paneque, M ;
Sellin, M ;
Carmona, E ;
Pérez, PJ ;
Gutiérrez-Puebla, E ;
Monge, A ;
Ruiz, C .
NEW JOURNAL OF CHEMISTRY, 2005, 29 (01) :109-115
[8]   The global carbon cycle:: A test of our knowledge of earth as a system [J].
Falkowski, P ;
Scholes, RJ ;
Boyle, E ;
Canadell, J ;
Canfield, D ;
Elser, J ;
Gruber, N ;
Hibbard, K ;
Högberg, P ;
Linder, S ;
Mackenzie, FT ;
Moore, B ;
Pedersen, T ;
Rosenthal, Y ;
Seitzinger, S ;
Smetacek, V ;
Steffen, W .
SCIENCE, 2000, 290 (5490) :291-296
[9]   The organometallic chemistry of carbon dioxide [J].
Gibson, DH .
CHEMICAL REVIEWS, 1996, 96 (06) :2063-2095
[10]   Introduction: Polyoxometalates - Multicomponent molecular vehicles to probe fundamental issues and practical problems [J].
Hill, CL .
CHEMICAL REVIEWS, 1998, 98 (01) :1-2