A new three-dimensional inorganic-organic hybrid fluorinated-iron(III) arsenate:: (C6H14N2)[Fe3(HASO4)2(AsO4)F4]0.5H2O.: Hydrothermal synthesis, crystal structure, and spectroscopic and magnetic properties

被引：27

作者：

Bazán, B

Mesa, JL

Pizarro, JL

Goñi, A

Lezama, L

Arriortua, MI

Rojo, T

机构：

[1] Univ Basque Country, Fac Ciencias, Dept Quim Inorgan, E-48080 Bilbao, Spain

[2] Univ Basque Country, Fac Ciencias, Dept Mineral Petrol, E-48080 Bilbao, Spain

来源：

INORGANIC CHEMISTRY | 2001年 / 40卷 / 22期

关键词：

D O I：

10.1021/ic0103796

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new inorganic-organic hybrid fluorinated-iron(III) arsenate with the formula (C6H14N2)[Fe-3(HASO(4))(2)-(AsO4)F-4]0.5H(2)O is reported. The structure consists of a three-dimensional framework formed by chains and dimeric units of Fe(III) ions, which gives rise to layers interconnected by hydrogenarsenate anions. The ESR spectra are isotropic. Magnetic measurements indicate a three-dimensional antiferromagnetic ordering at low temperatures.

引用

页码：5691 / +

页数：5

共 31 条

[1]

[Anonymous], 1995, POWDER DIFFRACTION F

[2]

[Anonymous], INT TABLES XRAY CRYS

[3] A new inorganic-organic hybrid iron(III) arsenate:: (C2H10N2)[Fe(HAsO4)2(H2AsO4)](H2O).: Hydrothermal synthesis, crystal structure, and spectroscopic and magnetic properties [J].