An exponentially expanding mesh ideally suited to the fast and efficient simulation of diffusion processes at microdisc electrodes. 2. Application to chronoamperometry

被引:63
作者
Gavaghan, DJ
机构
[1] Univ Oxford, Comp Lab, Oxford OX1 3QD, England
[2] Univ Oxford, Radcliffe Infirm, Nuffield Dept Anaesthet, Oxford OX2 6HE, England
基金
英国惠康基金; 英国医学研究理事会;
关键词
chronoamperometry; exponentially expanding mesh; microdisc electrodes;
D O I
10.1016/S0022-0728(98)00226-5
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
In the first accompanying paper we derived an exponentially expanding mesh for use in the simulation of diffusion processes at microdisc electrodes. In this paper we use this strategy in obtaining a solution for chronoamperometry at a microdisc. We show that it is possible to obtain accuracy to better than 0.25% from a single simulation using the same mesh at all times of interest. Demands on computing resources are light, with a full simulation from switch on through to near steady state taking just a few minutes of CPU time. (C) 1998 Elsevier Science S.A. All rights reserved.
引用
收藏
页码:13 / 23
页数:11
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