Mathematical model for cathodic delamination using a porosity-pH relationship

被引：27

作者：

Allahar, Kerry N.

Orazem, Mark E. ^{[1
]}

Ogle, Kevin

机构：

[1] Univ Florida, Dept Chem Engn, Gainesville, FL 32611 USA

[2] IRSID, F-57214 Maizieres Les Metz, France

来源：

CORROSION SCIENCE | 2007年 / 49卷 / 09期

关键词：

modelling studies; oxygen reduction; paint coatings;

D O I：

10.1016/j.corsci.2007.03.024

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A mathematical model was developed to simulate the transient propagation of the cathodic delamination on a coated metal. The model employed porosity and the polarization kinetics at the metal-coating interface that were assumed to be dependent on the local pH. The simulations provided qualitative agreement with published experimental results for a zinc coated system characterized by extremely rapid cathodic delamination. The mathematical model described in this work provides a foundation on which more sophisticated models can be constructed. (C) 2007 Elsevier Ltd. All rights reserved.

引用

页码：3638 / 3658

页数：21

共 16 条

[1]

ALLAHAR K, 2003, THESIS U FLORIDA GAI

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