Formation of [60]fullerene nanoclusters with controlled size and morphology through the aid of supramolecular rod-coil diblock copolymers

被引:43
作者
Fujita, N [1 ]
Yamashita, T [1 ]
Asai, M [1 ]
Shinkai, S [1 ]
机构
[1] Kyushu Univ, Grad Sch Engn, Dept Chem & Biochem, Higashi Ku, Fukuoka 8128581, Japan
关键词
block copolymers; fullerenes; host-guest systems; nanostructures; supramolecular chemistry;
D O I
10.1002/anie.200461174
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
On the starting block: Polystyrene-block-poly(4-vinylpyridine) and a [60]fullerene carboxylic acid combine to form spherical supramolecular aggregates (see picture), the size and morphology of which can be controlled by changing the block composition ratio in the copolymer. The method is generally applicable to the construction of organic nanoparticles. © 2005 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:1257 / 1261
页数:5
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