Digital communication through intermolecular fluorescence modulation

被引:84
作者
Raymo, FM [1 ]
Giordani, S [1 ]
机构
[1] Univ Miami, Dept Chem, Ctr Supramol Sci, Coral Gables, FL 33146 USA
关键词
D O I
10.1021/ol015853q
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
[GRAPHICS] Ultraminiaturized processors incorporating molecular components can be developed only after devising efficient strategies to communicate signals at the molecular level. We have demonstrated that a three-state molecular switch responds to ultraviolet light, visible light, and H+, attenuating the emission intensity of a fluorescent probe. Intermolecular communication is responsible for the transduction of three input signals into a single optical output. The behaviour of the communicating ensemble of molecules corresponding to that of a logic circuit incorporating seven gates.
引用
收藏
页码:1833 / 1836
页数:4
相关论文
共 63 条
[1]   Electrochemically induced molecular motions in pseudorotaxanes: A case of dual-mode (oxidative and reductive) dethreading [J].
Asakawa, M ;
Ashton, PR ;
Balzani, V ;
Credi, A ;
Mattersteig, G ;
Matthews, OA ;
Montalti, M ;
Spencer, N ;
Stoddart, JF ;
Venturi, M .
CHEMISTRY-A EUROPEAN JOURNAL, 1997, 3 (12) :1992-1996
[2]  
Asakawa M, 2000, ADV MATER, V12, P1099, DOI 10.1002/1521-4095(200008)12:15<1099::AID-ADMA1099>3.0.CO
[3]  
2-2
[4]  
Balzani V, 2000, ANGEW CHEM INT EDIT, V39, P3348, DOI 10.1002/1521-3773(20001002)39:19<3348::AID-ANIE3348>3.0.CO
[5]  
2-X
[6]  
Bard A., 1994, INTEGRATED CHEM SYST
[7]   Spiropyrans and spirooxazines for memories and switches [J].
Berkovic, G ;
Krongauz, V ;
Weiss, V .
CHEMICAL REVIEWS, 2000, 100 (05) :1741-1753
[8]  
Bertelson R.C., 1971, Photochromism, VIII, P45
[9]  
Bertelson RC, 1999, T APPL CHEM, V1, P11
[10]   Are single molecular wires conducting? [J].
Bumm, LA ;
Arnold, JJ ;
Cygan, MT ;
Dunbar, TD ;
Burgin, TP ;
Jones, L ;
Allara, DL ;
Tour, JM ;
Weiss, PS .
SCIENCE, 1996, 271 (5256) :1705-1707