Visible light-driven water oxidation-from molecular catalysts to photoelectrochemical cells

被引：200

作者：

Duan, Lele ^{[1
]}

Tong, Lianpeng ^{[1
]}

Xu, Yunhua ^{[1
]}

Sun, Licheng ^{[1
,2
]}

机构：

[1] Royal Inst Technol KTH, Dept Chem, Sch Chem Sci & Engn, S-10044 Stockholm, Sweden

[2] Dalian Univ Technol DUT, DUT KTH Joint Educ & Res Ctr Mol Devices, State Key Lab Fine Chem, Dalian 116024, Peoples R China

来源：

ENERGY & ENVIRONMENTAL SCIENCE | 2011年 / 4卷 / 09期

基金：

中国国家自然科学基金;

关键词：

MONONUCLEAR RUTHENIUM COMPLEXES; OXYGEN-EVOLVING CATALYST; TRANSITION-METAL-COMPLEXES; PHOTOSYSTEM-II; ARTIFICIAL PHOTOSYNTHESIS; ELECTROCHEMICAL OXIDATION; IRIDIUM COMPLEXES; CRYSTAL-STRUCTURE; RU(II) COMPLEXES; POLYMER MEMBRANE;

D O I：

10.1039/c1ee01276b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This perspective article reports the most significant advances in the field of water oxidation-from molecular water oxidation catalysts (WOCs) to photoelectrochemical cells. Different series of catalysts that can be applied in visible light-driven water oxidation catalysis are discussed in details and several key aspects of their catalytic mechanisms are introduced. In order to construct a water oxidation electrode from molecular catalysts, proper immobilization methods have to be employed. Herein, we present one section about how to attach catalysts onto an electrode/material surface. Finally, the state of the art photoelectrochemical cells that achieve visible light-driven water splitting are described.

引用

页码：3296 / 3313

页数：18

共 105 条

[1] Chemical approaches to artificial photosynthesis. 2 [J].

Alstrum-Acevedo, JH ;

Brennaman, MK ;

Meyer, TJ .

INORGANIC CHEMISTRY, 2005, 44 (20) :6802-6827

[2]

[Anonymous], 2010, ANGEW CHEM, DOI DOI 10.1002/ANGE.201003110

[3] Photochemical conversion of solar energy [J].

Balzani, Vincenzo ;

Credi, Alberto ;

Venturi, Margherita .

CHEMSUSCHEM, 2008, 1 (1-2) :26-58

[4] Cs9[(γ-PW10O36)2Ru4O5(OH)(H2O)4], a new all-inorganic, soluble catalyst for the efficient visible-light-driven oxidation of water [J].

Besson, Claire ;

Huang, Zhuangqun ;

Geletii, Yurii V. ;

Lense, Sheri ;

Hardcastle, Kenneth I. ;

Musaev, Djamaladdin G. ;

Lian, Tianquan ;

Proust, Anna ;

Hill, Craig L. .

CHEMICAL COMMUNICATIONS, 2010, 46 (16) :2784-2786

[5] Half-Sandwich Iridium Complexes for Homogeneous Water-Oxidation Catalysis [J].

Blakemore, James D. ;

Schley, Nathan D. ;

Balcells, David ;

Hull, Jonathan F. ;

Olack, Gerard W. ;

Incarvito, Christopher D. ;

Eisenstein, Odile ;

Brudvig, Gary W. ;

Crabtree, Robert H. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (45) :16017-16029

[6] The Ru-Hbpp Water Oxidation Catalyst [J].

Bozoglian, Fernando ;

Romain, Sophie ;

Ertem, Mehmed Z. ;

Todorova, Tanya K. ;

Sens, Cristina ;

Mola, Joaquim ;

Rodriguez, Montserrat ;

Romero, Isabel ;

Benet-Buchholz, Jordi ;

Fontrodona, Xavier ;

Cramer, Christopher J. ;

Gagliardi, Laura ;

Llobet, Antoni .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (42) :15176-15187

[7]

Brimblecombe R, 2008, ANGEW CHEM, V120, P7445

[8] Sustained water oxidation photocatalysis by a bioinspired manganese cluster [J].

Brimblecombe, Robin ;

Swiegers, Gerhard F. ;

Dismukes, G. Charles ;

Spiccia, Leone .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (38) :7335-7338

[9] Solar Driven Water Oxidation by a Bioinspired Manganese Molecular Catalyst [J].

Brimblecombe, Robin ;

Koo, Annette ;

Dismukes, G. Charles ;

Swiegers, Gerhard F. ;

Spiccia, Leone .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (09) :2892-+

[10] Sustained Water Oxidation by [Mn4O4]7+ Core Complexes Inspired by Oxygenic Photosynthesis [J].

Brimblecombe, Robin ;

Kolling, Derrick R. J. ;

Bond, Alan M. ;

Dismukes, G. Charles ;

Swiegers, Gerhard F. ;

Spiccia, Leone .

INORGANIC CHEMISTRY, 2009, 48 (15) :7269-7279

← 1 2 3 4 5 6 7 8 9 10 →