Raman spectra of gallium sulfide based glasses

被引：93

作者：

Tverjanovich, A ^{[1
]}

Tveryanovich, YS ^{[1
]}

Loheider, S ^{[1
]}

机构：

[1] FREE UNIV BERLIN,INST EXPT PHYS,D-1000 BERLIN,GERMANY

来源：

JOURNAL OF NON-CRYSTALLINE SOLIDS | 1996年 / 208卷 / 1-2期

关键词：

D O I：

10.1016/S0022-3093(96)00415-2

中图分类号：

TQ174 [陶瓷工业]; TB3 [工程材料学];

学科分类号：

0805 ; 080502 ;

摘要：

Raman investigation of glasses xGeS(2)-Ga2S3-yMCl, Ga2S3-2MCl (where M = Ag, Tl, Rb, Cs) and melt Ga2S3-2CsCl has been carried out for various x and y. Raman spectra have been interpreted in the frame of the model that gallium is fourfold coordinated in the chalcogenide/halide glasses and forms complex anions such as [GaS3/2Cl](1-). Stability of these units and type of their interconnection (corner shared or edge shared tetrahedra) depends on cation radius of a metal and correlates with glass-forming ability.

引用

页码：49 / 55

页数：7

共 19 条

[1]

BAIDAKOVA OL, 1991, VESTNIC LENINGR ST N, V11, P96

[2] INFRA-RED AND RAMAN SPECTRA OF DIMERIC GALLIUM TRIHALIDES [J].

BALLS, A ;

DOWNS, AJ ;

GREENWOO.NN ;

STRAUGHA.BP .

TRANSACTIONS OF THE FARADAY SOCIETY, 1966, 62 (519P) :521-&

[3] VIBRATIONAL-SPECTRA OF THE VITREOUS GA2S3-NA2S SYSTEM [J].

BARNIER, S ;

PALAZZI, M ;

MASSOT, M ;

JULIEN, C .

SOLID STATE IONICS, 1990, 44 (1-2) :81-86

[4] VIBRATIONAL SPECTRUM OF GA2CL6 [J].

BEATTIE, IR ;

GILSON, T ;

COCKING, P .

JOURNAL OF THE CHEMICAL SOCIETY A -INORGANIC PHYSICAL THEORETICAL, 1967, (04) :702-&

[5]

BELL RP, 1945, PROC R SOC LON SER-A, V183, P357, DOI 10.1098/rspa.1945.0008

[6] RAMAN-STUDY OF GALLIUM CHLOROSULFIDES IN CHLORIDE MELTS [J].

BERG, RW ;

BJERRUM, NJ .

POLYHEDRON, 1983, 2 (03) :179-181

[7]

BORISOVA ZU, 1991, INTERACTION METAL CH, P252

[8]

FELTZ A, 1976, STRUCTURE PROPERTIES, P88

[9]

FONTANA MP, 1988, PHILOS MAG B, V56, P507

[10] THEORY FOR 1ST-ORDER VIBRATIONAL-SPECTRA OF DISORDERED SOLIDS [J].

GALEENER, FL ;

SEN, PN .

PHYSICAL REVIEW B, 1978, 17 (04) :1928-1933

← 1 2 →