Diaquabis(nicotinamide)bis(o-sulfobenzimidato-N)-cadmium(II)

被引：7

作者：

Çakir, S

Naumov, P

Bulut, I

Biçer, E

Çakir, O

Jovanovski, G

Razak, IA

Chantrapromma, S

Fun, HK

Ng, SW ^{[1
]}

机构：

[1] Univ Malaya, Inst Postgrad Studies, Kuala Lumpur 50603, Malaysia

[2] Ondokuz Mayis Univ, Fac Arts & Sci, Dept Chem, TR-55139 Kurupelit, Turkey

[3] Sv Kinl I Metodij Univ, Inst Chem, MK-1001 Skopje, Macedonia

[4] Univ Sains Malaysia, Sch Phys, Xray Crystallog Unit, George Town 11800, Malaysia

[5] Prince Songkla Univ, Fac Sci, Dept Chem, Songkhla 90112, Thailand

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2001年 / 57卷

关键词：

D O I：

10.1107/S1600536801014453

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The Cd atom in the title compound, [Cd(C7H4NO3S)(2) (C6H6N2O)(2) (H2O)(2)], lies on an inversion centre and is six-coordinate in an all-trans octahedral geometry. Hydrogen bonds involving a water molecule and the amido group of a nicotinamide ligand link adjacent molecules into layers.

引用

收藏

页码：m431 / m432

页数：2

相关论文

共 12 条

[1] Synthesis and spectroscopic studies of novel Cu(II), Co(II), Ni(II) and Zn(II) mixed ligand complexes with saccharin and nicotinamide [J].

Çakir, S ;

Bulut, I ;

Naumov, P ;

Biçer, E ;

Çakir, O .

JOURNAL OF MOLECULAR STRUCTURE, 2001, 560 (1-3) :1-7

[2]

Johnson C. K., 1976, ORNL5138

[3] BONDING OF THE CARBONYL GROUP IN METAL SACCHARINATES - CORRELATION WITH THE INFRARED-SPECTRA [J].

JOVANOVSKI, G ;

SOPTRAJANOV, B .

JOURNAL OF MOLECULAR STRUCTURE, 1988, 174 :467-472

[4]

JOVANOVSKI G, 1990, B CHEM TECHNOL MACED, V8, P47

[5] On the geometry of the saccharinato ligand/ion in the metal saccharinates: Crystallographic survey and theoretical study [J].

Naumov, P ;

Jovanovski, G .

STRUCTURAL CHEMISTRY, 2000, 11 (01) :19-33

[6] Vibrational study and spectra-structure correlations in ammonium saccharinate: comparison with the alkali saccharinates [J].

Naumov, P ;

Jovanovski, G .

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2000, 56 (07) :1305-1318

[7] On the coordination in metal saccharinates. Implications for bond-order models of metal-ligand binding [J].

Naumov, P ;

Jovanovski, G .

JOURNAL OF COORDINATION CHEMISTRY, 2001, 54 (01) :63-79

[8] Outer-sphere coordination, N-coordination and O-coordination of the deprotonated saccharin in copper(II) saccharinato complexes.: Implications for the saccharinato carbonyl stretching frequency [J].

Naumov, P ;

Jovanovski, G ;

Drew, MGB ;

Ng, SW .

INORGANICA CHIMICA ACTA, 2001, 314 (1-2) :154-162

[9] Spectra-structure correlations in solid metal saccharinates. I. The carbonyl stretchings [J].

Naumov, P ;

Jovanovski, G .

JOURNAL OF MOLECULAR STRUCTURE, 2001, 563 :335-339

[10]

Sheldrick G. M., 1997, SHELXS 97 PROGRAM CR