Morphology of the Si-ZnO interface

被引:47
作者
Meier, U [1 ]
Pettenkofer, C [1 ]
机构
[1] Hahn Meitner Inst Berlin GmbH, D-14109 Berlin, Germany
关键词
photoemission; zincoxide; heterostructure; interfaces;
D O I
10.1016/j.apsusc.2005.02.039
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
For Si-ZnO heterostructures, prepared by magnetron sputtering, the interface morphology is studied by XPS and UPS. ZnO films On Si(I 1 1) Surfaces (H-termination and 7 x 7) were prepared by magnetron sputtering and metal organic molecular beam epitaxy (MOMBE) and are investigated in well defined deposition steps and the interface properties were studied ill situ. All samples were handled in Situ under ultra high vacuum (UHV) conditions. Up to five different interface phases were detected depending oil ZnO preparation. Beside a SiOx film induced by the sputter process, ZnO and Zn2SiO4 phases are resolved. In addition hydrogen. appearing as Zn-OHx, is found in considerable concentrations in the films. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:1139 / 1146
页数:8
相关论文
共 20 条
[1]   Optically pumped lasing of ZnO at room temperature [J].
Bagnall, DM ;
Chen, YF ;
Zhu, Z ;
Yao, T ;
Koyama, S ;
Shen, MY ;
Goto, T .
APPLIED PHYSICS LETTERS, 1997, 70 (17) :2230-2232
[2]  
CARDONA M, THIN FILMS SMALL PAR
[3]   Experimental confirmation of the predicted shallow donor hydrogen state in zinc oxide [J].
Cox, SFJ ;
Davis, EA ;
Cottrell, SP ;
King, PJC ;
Lord, JS ;
Gil, JM ;
Alberto, HV ;
Vilao, RC ;
Duarte, JP ;
de Campos, NA ;
Weidinger, A ;
Lichti, RL ;
Irvine, SJC .
PHYSICAL REVIEW LETTERS, 2001, 86 (12) :2601-2604
[4]  
DAKE LS, 1992, SURF INTERFACE ANAL, V18, P71
[5]   Characterization of a magnetron sputtering discharge with simultaneous RF- and DC-excitation of the plasma for the deposition of transparent and conductive ZnO:Al-films [J].
Ellmer, K ;
Cebulla, R ;
Wendt, R .
SURFACE & COATINGS TECHNOLOGY, 1998, 98 (1-3) :1251-1256
[6]   Solar cell efficiency tables (Version 22) [J].
Green, MA ;
Emery, K ;
King, DL ;
Igari, S ;
Warta, W .
PROGRESS IN PHOTOVOLTAICS, 2003, 11 (05) :347-352
[7]   CHEMICAL AND ELECTRONIC-STRUCTURES OF THE SIO2-SI INTERFACE [J].
HOLLINGER, G .
APPLIED SURFACE SCIENCE, 1981, 8 (03) :318-336
[8]   Structure of ultrathin SiO2/Si(111) interfaces studied by photoelectron spectroscopy [J].
Keister, JW ;
Rowe, JE ;
Kolodziej, JJ ;
Niimi, H ;
Tao, HS ;
Madey, TE ;
Lucovsky, G .
JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A, 1999, 17 (04) :1250-1257
[9]   ZINC-OXIDE N-SI JUNCTION SOLAR-CELLS PRODUCED BY SPRAY-PYROLYSIS METHOD [J].
KOBAYASHI, H ;
MORI, H ;
ISHIDA, T ;
NAKATO, Y .
JOURNAL OF APPLIED PHYSICS, 1995, 77 (03) :1301-1307
[10]   All-fiber acoustooptic phase modulators using chemical vapor deposition zinc oxide films [J].
Koch, MH ;
Janos, M ;
Lamb, RN ;
Sceats, MG ;
Minasian, RA .
JOURNAL OF LIGHTWAVE TECHNOLOGY, 1998, 16 (03) :472-476