Programmed Morphological Transitions of Multisegment Assemblies by Molecular Chaperone Analogues

被引：34

作者：

Boekhoven, Job ^{[1
]}

Brizard, Aurelie M. ^{[1
]}

van Rijn, Patrick ^{[1
]}

Stuart, Marc C. A. ^{[2
]}

Eelkema, Rienk ^{[1
]}

van Esch, Jan H. ^{[1
]}

机构：

[1] Delft Univ Technol, Dept Chem Engn, NL-2628 BL Delft, Netherlands

[2] Univ Groningen, Groningen Biomol Sci & Biotechnol Inst, NL-9747 AG Groningen, Netherlands

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 51期

关键词：

amphiphiles; gelators; morphological transitions; self-assembly; surfactants; WEIGHT HYDROGELATORS; GEL;

D O I：

10.1002/anie.201102364

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A multisegment amphiphile, made of a gelator and a surfactant, self-assembles into architectures with properties inherited from both segments. By addition of a surfactant, the surfactant segment of the amphiphile is selectively switched off, leading to the formation of fibrils. The addition of urea or hexafluoroisopropyl alcohol (HFIP) switches off the gelator segment, giving micelles. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

收藏

页码：12285 / 12289

页数：5

相关论文

共 32 条

[1] Hierarchical self-assembly of chiral rod-like molecules as a model for peptide β-sheet tapes, ribbons, fibrils, and fibers [J].

Aggeli, A ;

Nyrkova, IA ;

Bell, M ;

Harding, R ;

Carrick, L ;

McLeish, TCB ;

Semenov, AN ;

Boden, N .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2001, 98 (21) :11857-11862

[2]

[Anonymous], 2004, ANGEW CHEM, DOI [10.1002/ange.200352396, DOI 10.1002/ANGE.200352396]

[3] Size control and compartmentalization in self-assembled nano-structures of a multisegment amphiphile [J].

Boekhoven, Job ;

van Rijn, Patrick ;

Brizard, Aurelie M. ;

Stuart, Marc C. A. ;

van Esch, Jan H. .

CHEMICAL COMMUNICATIONS, 2010, 46 (20) :3490-3492

[4] The mechanisms of vesicle budding and fusion [J].

Bonifacino, JS ;

Glick, BS .

CELL, 2004, 116 (02) :153-166

[5]

Brizard A., 2008, ANGEW CHEM, V120, P2093

[6] Preparation of nanostructures by orthogonal self-assembly of hydrogelators and surfactants [J].

Brizard, Aurelie ;

Stuart, Marc ;

van Bommel, Kjeld ;

Friggeri, Arianna ;

de Jong, Menno ;

van Esch, Jan .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (11) :2063-2066

[7] Self-assembled interpenetrating networks by orthogonal self assembly of surfactants and hydrogelators [J].

Brizard, Aurelie M. ;

Stuart, Marc C. A. ;

van Esch, Jan H. .

FARADAY DISCUSSIONS, 2009, 143 :345-357

[8] Equilibrium Study of Protein Denaturation by Urea [J].

Canchi, Deepak R. ;

Paschek, Dietmar ;

Garcia, Angel E. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (07) :2338-2344

[9] Energy transfer in self-assembled [n]-acene fibers involving ≥ 100 donors per acceptor [J].

Del Guerzo, A ;

Olive, AGL ;

Reichwagen, J ;

Hopf, H ;

Desvergne, JP .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (51) :17984-17985

[10] SYNTHESIS AND STRUCTURAL INVESTIGATION OF POLY(L-ALANYL-L-ALANYL-GLYCINE) [J].

DOYLE, BB ;

TRAUB, W ;

LORENZI, GP ;

BROWN, FR ;

BLOUT, ER .

JOURNAL OF MOLECULAR BIOLOGY, 1970, 51 (01) :47-&

← 1 2 3 4 →