Conducting polymer-based chemiresistive sensor for organic vapours

被引:27
作者
Rosa, RM [1 ]
Szulc, RL [1 ]
Li, RWC [1 ]
Gruber, J [1 ]
机构
[1] Univ Sao Paulo, Inst Quim, BR-05513970 Sao Paulo, Brazil
关键词
conducting polymers; electronic noses; gas sensors; poly(2-bromo-5-hexyloxy-p-phenylenevinylene); PPV;
D O I
10.1002/masy.200551116
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Poly(2-bromo-5-hexyloxy-p-phenylenevinylene), BHPPV, was electrochemically synthesized in 81% yield. The polymer presented high solubility in organic solvents, in spite of its relatively high molar weight (<(M)over bar (W)> = 80 000), and showed to be thermally resistant UP to 130 degrees C. Gas sensors made from thin films of CSA doped BHPPV, deposited on interdigitated electrodes, responded to five different solvents. Plots of relative response versus relative recovery showed good discrimination of the five solvents.
引用
收藏
页码:138 / 142
页数:5
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