Synthesis of bridged medium-sized rings through the intramolecular Pauson-Khand reaction

被引：39

作者：

Lovely, CJ ^{[1
]}

Seshadri, H

Wayland, BR

Cordes, AW

机构：

[1] Univ Texas, Dept Chem & Biochem, Arlington, TX 76019 USA

[2] Univ Arkansas, Dept Chem & Biochem, Fayetteville, AR 72701 USA

来源：

ORGANIC LETTERS | 2001年 / 3卷 / 16期

关键词：

D O I：

10.1021/ol016308s

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] A series of aromatic enynes containing steric buttressing elements were prepared and evaluated in the NMO-mediated Pauson-Khand cyclization. O-Allyl systems led to the expected angularly fused products, whereas the O-butenyl and O-pentenyl derivatives afforded the unprecedented bridge systems.

引用

页码：2607 / 2610

页数：4

共 19 条

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