Novel semisquaraine regioisomers: isolation, divergent chemical reactivity and photophysical properties

被引：11

作者：

Avirah, Rekha R. ^{[1
]}

Jyothish, Kuthanapillil ^{[1
]}

Suresh, Cherumuttathu H.

Suresh, Eringathodi ^{[2
]}

Ramaiah, Danaboyina ^{[1
]}

机构：

[1] Natl Inst Interdisciplinary Sci & Technol NIIST C, Chem Sci & Technol Div, Trivandrum 695019, Kerala, India

[2] Cent Salt & Marine Chem Res Inst, Bhavnagar 364002, Gujarat, India

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 48期

关键词：

HALOGENATED SQUARAINE DYES; PHOTODYNAMIC THERAPY; ELECTRONIC FACTORS; CYTOTOXICITY; RECOGNITION; CHEMISTRY; DESIGN; SENSOR;

D O I：

10.1039/c1cc15261k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A zwitterionic semisquaraine 1,3-regioisomer which exhibits distinct photophysical properties and chemical reactivity was isolated. Uniquely, this isomer has been identified as the reactive intermediate in the squaraine dye formation reaction rather than the neutral 1,2-isomer and opens up new avenues for the synthesis of novel dyes for optoelectronic applications.

引用

页码：12822 / 12824

页数：3

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