Ruthenium Nanoparticles Stabilized by N-Heterocyclic Carbenes: Ligand Location and Influence on Reactivity

被引：184

作者：

Lara, Patricia ^{[2
,3
]}

Rivada-Wheelaghan, Orestes ^{[4
]}

Conejero, Salvador ^{[4
]}

Poteau, Romuald ^{[1
]}

Philippot, Karine ^{[2
,3
]}

Chaudret, Bruno ^{[1
]}

机构：

[1] LPCNO, F-31077 Toulouse, France

[2] CNRS, LCC, F-31077 Toulouse, France

[3] Univ Toulouse, UPS, INPT, LCC, F-31077 Toulouse, France

[4] Univ Seville, CSIC, Inst Invest Quim, Dept Quim Inorgan, Seville 41092, Spain

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 50期

关键词：

nanoparticles; N-heterocyclic carbenes; ruthenium; solid-state NMR spectroscopy; surface reactivity; NHC LIGANDS; ORGANOMETALLIC CHEMISTRY; IONIC LIQUIDS; COMPLEXES; NMR; CATALYSIS; ACTIVATION; DYNAMICS;

D O I：

10.1002/anie.201106348

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

NHCs go nano: Ruthenium nanoparticles were formed from (cyclooctadiene) (cyclooctatriene)ruthenium(0) and stabilized by N-heterocyclic carbenes (NHCs). Solid-state NMR spectroscopy revealed both the coordination of the NHC ligands on the surface of the particles and their surface reactivity. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：12080 / 12084

页数：5

共 50 条

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[3]

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