A Modular Approach for the Synthesis of Nanostructured Hybrid Materials with Tailored Properties: The Simultaneous Twin Polymerization

被引:27
作者
Loeschner, Tina [1 ]
Mehner, Alexander [1 ]
Grund, Silke [1 ]
Seifert, Andreas [1 ]
Pohlers, Andreas [3 ]
Lange, Arno [2 ]
Cox, Gerhard [2 ]
Haehnle, Hans-Joachim [2 ]
Spange, Stefan [1 ]
机构
[1] Tech Univ Chemnitz, Dept Polymer Chem, Inst Chem, D-09111 Chemnitz, Germany
[2] BASF SE, D-67056 Ludwigshafen, Germany
[3] Tech Univ Chemnitz, Inst Phys, Dept Xray & Neutron Diffractometry, D-09111 Chemnitz, Germany
关键词
nanostructures; organic-inorganic hybrid materials; polymerization; synthetic methods; twin polymerization; INORGANIC COMPOSITE-MATERIALS; SOL-GEL PROCESS; FURFURYL ALCOHOL; ACID CONTENT; NANOCOMPOSITES; GLASSES; SYSTEMS;
D O I
10.1002/anie.201108011
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A third twin: Homopolymers are formed by the copolymerization of two twin monomers. Using the new method of simultaneous twin polymerization, complex hybrid materials can be synthesized in a targeted manner (see scheme), in which, depending upon the combination of twin monomers used, nanostructured hybrid materials with different compositions and properties can be obtained. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:3258 / 3261
页数:4
相关论文
共 24 条
[1]   Nanoscale Tungsten Trioxide Synthesized by In Situ Twin Polymerization [J].
Boettger-Hiller, Falko ;
Lungwitz, Ralf ;
Seifert, Andreas ;
Hietschold, Michael ;
Schlesinger, Maik ;
Mehring, Michael ;
Spange, Stefan .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (47) :8878-8881
[2]  
Bottger-Hiller F., 2009, ANGEW CHEM, V121, P9039
[3]   Synthesis of laterally linked poly(tetrahydrofuran)-poly(methyl methacrylate) block copolymers via use of a "Jekyll and Hyde" comonomer [J].
Chagneux, N. ;
Camerlynck, S. ;
Hamilton, E. ;
Vilela, F. M. L. ;
Sherrington, D. C. .
MACROMOLECULES, 2007, 40 (09) :3183-3189
[4]   UV-radiation curing of acrylate/epoxide systems [J].
Decker, C ;
Viet, TNT ;
Decker, D ;
Weber-Koehl, E .
POLYMER, 2001, 42 (13) :5531-5541
[5]  
ELLSWORTH MW, 1992, MATER RES SOC SYMP P, V274, P67, DOI 10.1557/PROC-274-67
[6]  
Grund S., 2007, ANGEW CHEM, V119, P636, DOI DOI 10.1002/ANGE.200504327
[7]  
Grund S., 2010, THESIS U CHEMNITZ
[8]   Nanocomposites prepared by twin polymerization of a single-source monomer [J].
Grund, Silke ;
Kempe, Patrick ;
Baumann, Gisela ;
Seifert, Andreas ;
Spange, Stefan .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (04) :628-632
[9]   RUBBER-LIKE ELASTICITY OF ORGANICALLY MODIFIED SILICATES [J].
HU, Y ;
MACKENZIE, JD .
JOURNAL OF MATERIALS SCIENCE, 1992, 27 (16) :4415-4420
[10]  
HUANG HH, 1985, POLYM BULL, V14, P557