Synthesis and characterization of extended tetrathiafulvalenes with di-, tri-, and tetraethynylethene cores

被引:41
作者
Andersson, AS
Qvortrup, K
Torbensen, ER
Mayer, JP
Gisselbrecht, JP
Boudon, C
Gross, M
Kadziola, A
Kilså, K
Nielsen, MB
机构
[1] Univ Copenhagen, Dept Chem, DK-2100 Copenhagen, Denmark
[2] Univ So Denmark, Dept Chem, DK-5230 Odense, Denmark
[3] Univ Strasbourg, Lab Electrochem & Chim Phys Corps Solide, CNRS, UMR 7512, F-67000 Strasbourg, France
关键词
alkynes; conjugation; c-c coupling; cross-coupling; donor-acceptor systems;
D O I
10.1002/ejoc.200500287
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A selection of new acetylenic building blocks has been prepared and employed for construction of extended tetrathia-fulvalenes (TTFs) and novel donor-acceptor molecules based on either diethynylethene (DEE), triethynylethene (TriEE), or tetraethynylethene (TEE) cores. The novel chromophores were studied for their redox, chromophoric, and structural properties, which have provided fundamental structure-property relationships. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005).
引用
收藏
页码:3660 / 3671
页数:12
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