A detailed techno-economic analysis of heat integration in high temperature electrolysis for efficient hydrogen production

被引:87
作者
Buttler, Alexander [1 ]
Koltun, Roman [1 ]
Wolf, Romano [1 ]
Spliethoff, Hartmut [1 ,2 ]
机构
[1] Tech Univ Munich, Lehrstuhl Energiesyst, D-85748 Garching, Germany
[2] ZAE Bayern, D-85748 Garching, Germany
关键词
Solid oxide electrolysis; High temperature heat integration; Isothermal operation; Techno-economic analysis; OXIDE STEAM ELECTROLYZER; WATER ELECTROLYSIS; MODEL; CELL; PERFORMANCE; SIMULATION; BEHAVIOR; ECONOMY;
D O I
10.1016/j.ijhydene.2014.10.048
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070305 [高分子化学与物理];
摘要
The effect of high temperature heat utilization in solid oxide electrolysis on efficiency and hydrogen specific cell area is investigated based on a detailed 1-D electrochemical model validated with literature data. A first feasibility analysis indicates that the mean heat transfer required to maintain isothermal conditions as a function of heat integration shows a maximum with 1426 W/m(2) at a heat utilization of 0.34 kWh/Nm(3) H-2, which seems to be technically achievable. Based on the assumption of future specific cell area costs of 1500 is an element of/m(2) high temperature heat integration of 0.24 kWh/Nm(3) is economically reasonable resulting in a reduction of the specific electric energy consumption by 7.8% (2.82 kWh/Nm(3)) compared to thermo-neutral operation. An extensive sensitivity analysis indicates increased electricity prices and higher lifetime of the solid oxide electrolysis cell (SOEC) stack as major parameters favoring direct heat utilization, while decreasing utilization for power-to-gas storage applications is counteracting. Copyright (C) 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:38 / 50
页数:13
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