Molecule-mimetic chemistry and mesoscale self-assembly

被引：203

作者：

Bowden, NB ^{[1
]}

Weck, M ^{[1
]}

Choi, IS ^{[1
]}

Whitesides, GM ^{[1
]}

机构：

[1] Harvard Univ, Dept Chem & Biol Chem, Cambridge, MA 02138 USA

来源：

ACCOUNTS OF CHEMICAL RESEARCH | 2001年 / 34卷 / 03期

关键词：

D O I：

10.1021/ar0000760

中图分类号：

O6 [化学];

学科分类号：

0703 [化学];

摘要：

Molecules are structured aggregates of atoms joined by chemical bonds; crystals are aggregates of molecules, interacting covalently or noncovalently. The work described in this Account uses molecules, crystals, and other forms of atomic/molecular matter to suggest principles that can be used in generating structured aggregates df millimeter-scale components, interacting through capillary interactions. The properties of these aggregates-that is, their "chemistry"-mimic aspects of the chemistry of molecules.

引用

页码：231 / 238

页数：8

共 54 条

[1]

Entropically driven microphase transitions in mixtures of colloidal rods and spheres [J].

Adams, M ;

Dogic, Z ;

Keller, SL ;

Fraden, S .

NATURE, 1998, 393 (6683) :349-352

[2]

Perspectives on the physical chemistry of semiconductor nanocrystals [J].

Alivisatos, AP .

JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (31) :13226-13239

[3]

Organization of 'nanocrystal molecules' using DNA [J].

Alivisatos, AP ;

Johnsson, KP ;

Peng, XG ;

Wilson, TE ;

Loweth, CJ ;

Bruchez, MP ;

Schultz, PG .

NATURE, 1996, 382 (6592) :609-611

[4]

Mesoscale self-assembly of hexagonal plates using lateral capillary forces: Synthesis using the "capillary bond" [J].

Bowden, N ;

Choi, IS ;

Grzybowski, BA ;

Whitesides, GM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (23) :5373-5391

[5]

Self-assembly of mesoscale objects into ordered two-dimensional arrays [J].

Bowden, N ;

Terfort, A ;

Carbeck, J ;

Whitesides, GM .

SCIENCE, 1997, 276 (5310) :233-235

[6]

Mesoscale self-assembly: Capillary bonds and negative menisci [J].

Bowden, N ;

Oliver, SRJ ;

Whitesides, GM .

JOURNAL OF PHYSICAL CHEMISTRY B, 2000, 104 (12) :2714-2724

[7]

Crystal engineering and organometallic architecture [J].

Braga, D ;

Grepioni, F ;

Desiraju, GR .

CHEMICAL REVIEWS, 1998, 98 (04) :1375-1405

[8]

Design and self-assembly of open, regular, 3D mesostructures [J].

Breen, TL ;

Tien, J ;

Oliver, SRJ ;

Hadzic, T ;

Whitesides, GM .

SCIENCE, 1999, 284 (5416) :948-951

[9]

OPTICAL BINDING [J].

BURNS, MM ;

FOURNIER, JM ;

GOLOVCHENKO, JA .

PHYSICAL REVIEW LETTERS, 1989, 63 (12) :1233-1236

[10]

Mesoscale folding: A physical realization of an abstract, 2D lattice model for molecular folding [J].

Choi, IS ;

Weck, M ;

Jeon, NL ;

Whitesides, GM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (48) :11997-11998

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