Synthesis and theoretical studies of a diorganohydridoplatinum(IV) complex, PtHMe(2){(pz)(3)BH-N,N',N''}([(pz)(3)BH](-)=tris(pyrazol-1-yl)borate)

被引：85

作者：

Canty, AJ ^{[1
]}

Dedieu, A ^{[1
]}

Jin, H ^{[1
]}

Milet, A ^{[1
]}

Richmond, MK ^{[1
]}

机构：

[1] UNIV STRASBOURG 1, LAB CHIM QUANT, CNRS, UPR 139, F-67000 STRASBOURG, FRANCE

来源：

ORGANOMETALLICS | 1996年 / 15卷 / 12期

关键词：

D O I：

10.1021/om950867j

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The platinum(II) tris(pyrazol-1-yl)borate complex [PtMe(2){(pz)(3)BH-N,N'}]- reacts with phenol or aqueous HBF4 in acetone to form the dimethylhydridoplatinum(IV) complex PtHMe(2){(pz)3BH-N,N',N ''). The complex decomposes above similar to 140 degrees C in toluene-d(8) to give methane. Theoretical calculations at the SCF and MP2 levels for the species PtXMe(2){(H2C=N-NH)(3)BH-N,N',N ''} (where X = H, OH, Me and the fragment [(H2C=N-NH)(3)BH](-) is a model for [(pz)(3)BH](-)) yield geometries that compare well with structural reports for Pt(OH)Me(2){(pz)(3)BH} and PdMe(3){(pz)(3)BH}.

引用

页码：2845 / 2847

页数：3

共 24 条

[1] Anderson G. K., 1995, COMPREHENSIVE ORGANO, P431
[2] THE ROLE OF TRANSITION-METAL ATOMS AS HYDROGEN-BOND ACCEPTORS - A NEUTRON-DIFFRACTION STUDY OF [NPRN4]2[PTCL4].CIS-[PTCL2(NH2ME)2] AT 20-K
BRAMMER, L
CHARNOCK, JM
GOGGIN, PL
GOODFELLOW, RJ
ORPEN, AG
KOETZLE, TF
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, (07): : 1789 - 1798
[3] HYDROGEN-BONDS INVOLVING TRANSITION-METAL CENTERS - A BRIEF REVIEW
BRAMMER, L
ZHAO, D
LADIPO, FT
BRADDOCKWILKING, J
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 1995, 51 : 632 - 640
[4] COORDINATION CHEMISTRY OF DIMETHYLGOLD(III) - SYNTHESIS, STRUCTURAL STUDIES, AND FLUXIONAL BEHAVIOR OF COMPLEXES WITH POLYDENTATE LIGANDS
BYERS, PK
CANTY, AJ
MINCHIN, NJ
PATRICK, JM
SKELTON, BW
WHITE, AH
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1985, (06): : 1183 - 1189
[5] SYNTHESIS AND CHARACTERIZATION OF AMBIENT-TEMPERATURE STABLE ORGANOPALLADIUM(IV) COMPLEXES, INCLUDING ARYL, ETA(1)-ALLYL, ETHYLPALLADIUM(IV), AND PALLADA(IV)CYCLOPENTANE COMPLEXES - STRUCTURES OF THE POLY(PYRAZOL-1-YL)BORATE COMPLEXES PDME(3)((PZ)(3)BH) AND PDME(3)((PZ)(4)B) AND 3 POLYMORPHS OF PDME(2)ET((PZ)(3)BH)
CANTY, AJ
JIN, H
ROBERTS, AS
SKELTON, BW
TRAILL, PR
WHITE, AH
[J]. ORGANOMETALLICS, 1995, 14 (01) : 199 - 206
[6] MECHANISMS OF D(8) ORGANOMETALLIC REACTIONS INVOLVING ELECTROPHILES AND INTRAMOLECULAR ASSISTANCE BY NUCLEOPHILES
CANTY, AJ
VANKOTEN, G
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1995, 28 (10) : 406 - 413
[7] OXIDATION REACTIONS USING WATER, HYDROGEN-PEROXIDE AND HALOGENS TO GIVE PALLAD(IV)CYCLOPENTANE COMPLEXES PDX(C4H8)((PZ)(3)BH) (X=OH, CL, BR, I) - THE CRYSTAL-STRUCTURE OF THE HYDROXOPLATINUM(IV) COMPLEX PT(OH) ME(2)((PZ)(3)BH), FORMED BY USE OF WATER AS AN OXIDANT
CANTY, AJ
FRITSCHE, SD
JIN, H
SKELTON, BW
WHITE, AH
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 490 (1-2) : C18 - C19
[8] COLLMAN JP, 1987, PRINCIPLES APPLICATI
[9] DEFELICE V, 1995, J ORGANOMET CHEM, V488, pC13
[10] Frisch M.J., 1995, GAUSSIAN 94 REVISION

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