A statistical model of fullerene formation based on quantum-mechanical calculations - I. The most probable precursors of fullerenes

被引:16
作者
Alekseev, NI [1 ]
Dyuzhev, GA [1 ]
机构
[1] Russian Acad Sci, AF Ioffe Physicotech Inst, St Petersburg 194021, Russia
基金
俄罗斯基础研究基金会;
关键词
D O I
10.1134/1.1372948
中图分类号
O59 [应用物理学];
学科分类号
摘要
An analysis is carried out of the carbon clusters that may be immediate precursors of fullerenes Using quantum chemistry methods it is shown that these can be two-ring clusters with a single bond between the rings. Possible initial steps of the transformation of a two-ring cluster into a fullerene have been outlined. (C) 2001 MAIK "Nauka/Interperiodica".
引用
收藏
页码:573 / 576
页数:4
相关论文
共 6 条
[1]  
ALEKSANDROV AL, 1995, ZH STRUKT KHIM, V36, P991
[2]   Production of fullerenes in gas discharge plasmas. I. Kinetics of fullerene formation from polycyclic structures [J].
Alekseev, NI ;
Dyuzhev, GA .
TECHNICAL PHYSICS, 1999, 44 (09) :1093-1097
[3]  
Eyring H., 1980, Basic Chemical Kinetics
[4]   ANNEALING CARBON CLUSTER IONS - A MECHANISM FOR FULLERENE SYNTHESIS [J].
HUNTER, JM ;
FYE, JL ;
ROSKAMP, EJ ;
JARROLD, MF .
JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (07) :1810-1818
[5]   KINETICS OF CARBON CLUSTER ISOMERIZATION - FROM TRICYCLIC RINGS TO FULLERENES [J].
SCHWEIGERT, VA ;
ALEXANDROV, AL ;
MOROKOV, YN ;
BEDANOV, VM .
CHEMICAL PHYSICS LETTERS, 1995, 235 (3-4) :221-229
[6]   A cycloaddition model for fullerene formation [J].
Strout, DL ;
Scuseria, GE .
JOURNAL OF PHYSICAL CHEMISTRY, 1996, 100 (16) :6492-6498