Ferrocenylalanes:: Solid-state and solution structures of some new aluminum-bridged ansa-ferrocenes

被引：38

作者：

Braunschweig, H ^{[1
]}

Burschka, C ^{[1
]}

Clentsmith, GKB ^{[1
]}

Kupfer, T ^{[1
]}

Radacki, K ^{[1
]}

机构：

[1] Univ Wurzburg, Inst Anorgan Chem, D-97074 Wurzburg, Germany

来源：

INORGANIC CHEMISTRY | 2005年 / 44卷 / 14期

关键词：

D O I：

10.1021/ic0501925

中图分类号：

O61 [无机化学];

学科分类号：

070301 [无机化学]; 081704 [应用化学];

摘要：

Addition of dilithiated ferrocene to AlEt2Cl and AI(kappa(2)-C,NNMe2-CH2C6H4)Cl-2 yields the trimeric ferrocenyl derivative 1 and the dimeric [1,1']-ferrocenophane 2, respectively. Solution spectroscopy is consistent with the solid-state structures, which reveal unusual and unprecedented bonding around the aluminum centers.

引用

页码：4906 / 4908

页数：3

共 28 条

[1]

Organoiron polymers [J].

Abd-El-Aziz, AS ;

Todd, EK .

COORDINATION CHEMISTRY REVIEWS, 2003, 246 (1-2) :3-52

[2]

A digalla[1.1]ferrocenophane and its coordination chemistry:: Synthesis and structure of [{Fe(η5-C5H4)2}2{GaMe}2] and of the adducts [{Fe(η5-C5H4)2}2GaMe(D)}2] (D = monodentate donor) and [Fe(η5-C5H4)2}2{GaMe}2D] (D = bidentate donor) [J].

Althoff, A ;

Jutzi, P ;

Lenze, N ;

Neumann, B ;

Stammler, A ;

Stammler, HG .

ORGANOMETALLICS, 2003, 22 (13) :2766-2774

[3]

The first 1,1′-digallylferrocene and a rodlike, polymeric donor-acceptor complex:: Synthesis, properties, and structure of [Fe(η5-C5H4GaMe2)2]n and [Fe(η5-C5H4GaMe2)2(C12H8N2)]n [J].

Althoff, A ;

Jutzi, P ;

Lenze, N ;

Neumann, B ;

Stammler, A ;

Stammler, HG .

ORGANOMETALLICS, 2002, 21 (14) :3018-3022

[4]

FERROCENYLALANES - PREPARATION AND PROPERTIES OF (ETA-C5H5)FE(ETA-C5H4AL2ME4CL) [J].

ATWOOD, JL ;

BAILEY, BL ;

KINDBERG, BL ;

COOK, WJ .

AUSTRALIAN JOURNAL OF CHEMISTRY, 1973, 26 (10) :2297-2298

[5]

SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF NOVEL FERROCENYLALANE DIMER [(ETA-C-5H-5)FE(ETA-C-5H-3)AL-2ME-3CL]2 [J].

ATWOOD, JL ;

SHOEMAKER, AL .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1976, (14) :536-537

[6]

Nucleophilically assisted and cationic ring-opening polymerization of tin-bridged [1]ferrocenophanes [J].

Baumgartner, T ;

Jäkle, F ;

Rulkens, R ;

Zech, G ;

Lough, AJ ;

Manners, I .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (34) :10062-10070

[7]

Synthesis, electronic structure, and novel reactivity of strained, boron-bridged [1]ferrocenophanes [J].

Berenbaum, A ;

Braunschweig, H ;

Dirk, R ;

Englert, U ;

Green, JC ;

Jäkle, F ;

Lough, AJ ;

Manners, I .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (24) :5765-5774

[8]

Incorporation of a first row element into the bridge of a strained metallocenophane: Synthesis of a boron-bridged [1]ferrocenophane [J].

Braunschweig, H ;

Dirk, R ;

Muller, M ;

Nguyen, P ;

Resendes, R ;

Gates, DP ;

Manners, I .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (21) :2338-2340

[9]

Synthesis and X-ray crystal structure of a urana[1]ferrocenophane, the first tris(1,1′-ferrocenylene) metal compound [J].

Bucaille, A ;

Le Borgne, T ;

Ephritikhine, M ;

Daran, JC .

ORGANOMETALLICS, 2000, 19 (23) :4912-4914

[10]

Frisch M. J., 2016, J AM CHEM SOC, DOI DOI 10.1021/JA205566W

← 1 2 3 →