Vapor-liquid equilibria for the ternary system ethanol + water+1-ethyl-3-methylimidazolium ethylsulfate and the corresponding binary systems containing the ionic liquid at 101.3 kPa

被引：112

作者：

Calvar, Noelia ^{[1
]}

Gonzalez, Begona ^{[1
]}

Gomez, Elena ^{[1
]}

Dominguez, Angeles ^{[1
]}

机构：

[1] Univ Vigo, Dept Chem Engn, Vigo 36310, Spain

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2008年 / 53卷 / 03期

关键词：

D O I：

10.1021/je700710d

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

In this work, experimental data of isobaric vapor-liquid equilibria (VLE) for the ternary system ethanol + water + 1-ethyl-3-methylimidazolium ethylsulfate (EMISE) and for the corresponding binary systems containing the ionic liquid (ethanol + EMISE, water + EMISE) were carried out at 101.3 kPa. VLE data of binary systems were correlated using the e-NRTL and NRTL equations. With the obtained parameters, we can predict the behavior of the ternary system. In addition, the ternary system was correlated using the NRTL equation. A study of the evolution of the ethanol + water azeotrope composition with different amounts of ionic liquid was made.

引用

收藏

页码：820 / 825

页数：6

相关论文

共 22 条

[1]

VLE for water plus ethanol plus 1-octanol mixtures. Experimental measurements and correlations [J].

Arce, A ;

MartinezAgeitos, J ;

Soto, A .

FLUID PHASE EQUILIBRIA, 1996, 122 (1-2) :117-129

[2]

Use of a green and cheap ionic liquid to purify gasoline octane boosters [J].

Arce, Alberto ;

Rodriguez, Hector ;

Soto, Ana .

GREEN CHEMISTRY, 2007, 9 (03) :247-253

[3]

Experimental determination, correlation, and prediction of physical properties of the ternary mixtures ethanol plus water with 1-octyl-3-methylimidazolium chloride and 1-ethyl-3-methylimidazolium ethylsulfate [J].

Calvar, Noelia ;

Gomez, Elena ;

Gonzalez, Begona ;

Dominguez, Angeles .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2007, 52 (06) :2529-2535

[4]

LOCAL COMPOSITION MODEL FOR EXCESS GIBBS ENERGY OF ELECTROLYTE SYSTEMS .1. SINGLE SOLVENT, SINGLE COMPLETELY DISSOCIATED ELECTROLYTE SYSTEMS [J].

CHEN, CC ;

BRITT, HI ;

BOSTON, JF ;

EVANS, LB .

AICHE JOURNAL, 1982, 28 (04) :588-596

[5]

Measurement and prediction of vapor-liquid equilibria of ternary systems containing ionic liquids [J].

Döker, M ;

Gmehling, J .

FLUID PHASE EQUILIBRIA, 2005, 227 (02) :255-266

[6]

Physical properties of pure 1-ethyl-3-methylimidazolium ethylsulfate and its binary mixtures with ethanol and water at several temperatures [J].

Gomez, Elena ;

Gonzalez, Begona ;

Calvar, Noelia ;

Tojo, Emilia ;

Dominguez, Angeles .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2006, 51 (06) :2096-2102

[7]

Density and viscosity of several pure and water-saturated ionic liquids [J].

Jacquemin, J ;

Husson, P ;

Padua, AAH ;

Majer, V .

GREEN CHEMISTRY, 2006, 8 (02) :172-180

[8]

THERMODYNAMIC REPRESENTATION OF PHASE-EQUILIBRIA OF MIXED-SOLVENT ELECTROLYTE SYSTEMS [J].

MOCK, B ;

EVANS, LB ;

CHEN, CC .

AICHE JOURNAL, 1986, 32 (10) :1655-1664

[9]

MOCK B, 1984, P SUMM COMP SIM C, V1984, P558

[10]

DENSITY AND VISCOSITY OF MIXTURES OF NITROBENZENE WITH METHANOL, ETHANOL, PROPAN-1-OL, PROPAN-2-OL, BUTAN-1-OL, 2-METHYLPROPANE-1-OL, AND 2-METHYLPROPAN-2-OL AT 298.15 AND 303.15 K [J].

NIKAM, PS ;

JADHAV, MC ;

HASAN, M .

JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1995, 40 (04) :931-934