Application of a chiral metal-organic framework in enantioselective separation

被引：157

作者：

Padmanaban, Mohan ^{[1
]}

Mueller, Philipp ^{[2
]}

Lieder, Christian ^{[3
]}

Gedrich, Kristina ^{[2
]}

Gruenker, Ronny ^{[2
]}

Bon, Volodymyr ^{[2
]}

Senkovska, Irena ^{[2
]}

Baumgaertner, Sandra ^{[3
]}

Opelt, Sabine ^{[3
]}

Paasch, Silvia ^{[4
]}

Brunner, Eike ^{[4
]}

Glorius, Frank ^{[1
]}

Klemm, Elias ^{[3
]}

Kaskel, Stefan ^{[2
]}

机构：

[1] Univ Munster, NRW Grad Sch Chem, Inst Organ Chem, D-48149 Munster, Germany

[2] Tech Univ Dresden, Dept Inorgan Chem, D-01062 Dresden, Germany

[3] Univ Stuttgart, Inst Chem Technol, D-70569 Stuttgart, Germany

[4] Tech Univ Dresden, Dept Bioanalyt Chem, D-01062 Dresden, Germany

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 44期

关键词：

SELECTIVE ADSORPTION; HETEROGENEOUS CATALYSIS; XYLENE ISOMERS; MIL-47; MOFS;

D O I：

10.1039/c1cc14893a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A modular approach for the synthesis of highly ordered porous and chiral auxiliary (Evans auxiliary) decorated metal-organic frameworks is developed. Our synthesis strategy, which uses known porous structures as model materials for incorporation of chirality via linker modification, can provide access to a wide range of porous materials suitable for enantioselective separation and catalysis. Chiral analogues of UMCM-1 have been synthesized and investigated for the enantioseparation of chiral compounds in the liquid phase and first promising results are reported.

引用

页码：12089 / 12091

页数：3

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