A novel BF2-chelated azadipyrromethene-fullerene dyad: synthesis, electrochemistry and photodynamics

被引：95

作者：

Amin, Anu N. ^{[2
]}

El-Khouly, Mohamed E. ^{[1
,4
]}

Subbaiyan, Navaneetha K. ^{[3
]}

Zandler, Melvin E. ^{[2
]}

Fukuzumi, Shunichi ^{[1
,4
]}

D'Souza, Francis ^{[2
,3
]}

机构：

[1] Osaka Univ, Dept Mat & Life Sci, Grad Sch Engn, ALCA,JST, Suita, Osaka 5650871, Japan

[2] Wichita State Univ, Dept Chem, Wichita, KS 67260 USA

[3] Univ N Texas, Dept Chem, Denton, TX 76203 USA

[4] Ewha Womans Univ, Dept Bioinspired Sci, Seoul 120750, South Korea

来源：

CHEMICAL COMMUNICATIONS | 2012年 / 48卷 / 02期

基金：

美国国家科学基金会;

关键词：

ELECTRON-TRANSFER; BEHAVIOR; SYSTEMS;

D O I：

10.1039/c1cc16071k

中图分类号：

O6 [化学];

学科分类号：

070301 [无机化学];

摘要：

The synthesis, structure, electrochemistry and photodynamics of a BF2-chelated azadipyrromethene-fullerene dyad are reported in comparison with BF2-chelated azadipyrromethene without fullerene. The attachment of fullerene resulted in efficient generation of the triplet excited state of the azadipyrromethene via photoinduced electron transfer.

引用

页码：206 / 208

页数：3

共 29 条

[1]

Syntheses, Electrochemistry, and Photodynamics of Ferrocene-Azadipyrromethane Donor-Acceptor Dyads and Triads [J].

Amin, Anu N. ;

El-Khouly, Mohamed E. ;

Subbaiyan, Navaneetha K. ;

Zandler, Melvin E. ;

Supur, Mustafa ;

Fukuzumi, Shunichi ;

D'Souza, Francis .

JOURNAL OF PHYSICAL CHEMISTRY A, 2011, 115 (35) :9810-9819

[2]

[Anonymous], 2003, GAUSS 03

[3]

Lighting the way ahead with boron dipyrromethene (Bodipy) dyes [J].

Benniston, Andrew C. ;

Copley, Graeme .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2009, 11 (21) :4124-4131

[4]

Self-assembled tetrapyrrole-fullerene and tetrapyrrole-carbon nanotube donor-acceptor hybrids for light induced electron transfer applications [J].

Chitta, Raghu ;

D'Souza, Francis .

JOURNAL OF MATERIALS CHEMISTRY, 2008, 18 (13) :1440-1471

[5]

Corrole-Fullerene Dyads: Formation of Long-Lived Charge-Separated States in Nonpolar Solvents [J].

D'Souza, Francis ;

Chitta, Raghu ;

Ohkubo, Kei ;

Tasior, Mariusz ;

Subbaiyan, Navaneetha K. ;

Zandler, Melvin E. ;

Rogacki, Maciek K. ;

Gryko, Daniel T. ;

Fukuzumi, Shunichi .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (43) :14263-14272

[6]

Formation, spectral, electrochemical, and photochemical behavior of zinc N-confused porphyrin coordinated to imidazole functionalized fullerene dyads [J].

D'Souza, Francis ;

Smith, Phillip M. ;

Rogers, Lisa ;

Zandler, Melvin E. ;

Islam, D. -M. Shafiqul ;

Araki, Yasuyaki ;

Ito, Osamu .

INORGANIC CHEMISTRY, 2006, 45 (13) :5057-5065

[7]

Supramolecular donor-acceptor hybrids of porphyrins/phthalocyanines with fullerenes/carbon nanotubes: electron transfer, sensing, switching, and catalytic applications [J].

D'Souza, Francis ;

Ito, Osamu .

CHEMICAL COMMUNICATIONS, 2009, (33) :4913-4928

[8]

Intermolecular and supramolecular photoinduced electron transfer processes of fullerene-porphyrin/phthalocyanine systems [J].

El-Khouly, ME ;

Ito, O ;

Smith, PM ;

D'Souza, F .

JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY C-PHOTOCHEMISTRY REVIEWS, 2004, 5 (01) :79-104

[9]

Molecular and supramolecular C60-oligophenylenevinylene conjugates [J].

Figueira-Duarte, Teresa M. ;

Gegout, Aline ;

Nierengarten, Jean-Francois .

CHEMICAL COMMUNICATIONS, 2007, (02) :109-119

[10]

Synthesis and Characterization of Boron Azadipyrromethene Single-Wall Carbon Nanotube Electron Donor-Acceptor Conjugates [J].

Flavin, Kevin ;

Lawrence, Katherine ;

Bartelmess, Juergen ;

Tasior, Mariusz ;

Navio, Cristina ;

Bittencourt, Carla ;

O'Shea, Donal F. ;

Guldi, Dirk M. ;

Giordani, Silvia .

ACS NANO, 2011, 5 (02) :1198-1206

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