Highly enantioselective rhodium-catalyzed conjugate addition of arylboronic acids to enones at room temperature

被引：27

作者：

Martina, SLX ^{[1
]}

Minnaard, AJ ^{[1
]}

Hessen, B ^{[1
]}

Feringa, BL ^{[1
]}

机构：

[1] Univ Groningen, Stratingh Inst, Dept Organ & Mol Inorgan Chem, NL-9747 AG Groningen, Netherlands

来源：

TETRAHEDRON LETTERS | 2005年 / 46卷 / 42期

关键词：

asymmetric 1,4-addition; arylboronic acid; rhodium-catalysis; phosphoramidite;

D O I：

10.1016/j.tetlet.2005.08.095

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The rhodium-phosphoramidite-catalyzed asymmetric conjugate addition of arylboronic acids to enones proceeds at room temperature using [Rh(OH)(cod)](2) or [RhCl(cod)](2)/KOH as stable and readily available catalyst precursors. (c) 2005 Published by Elsevier Ltd.

引用

页码：7159 / 7163

页数：5

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