The step-wise assembly of an undecanuclear heterotrimetallic cyanide cluster

被引:47
作者
Berlinguette, CP [1 ]
Dunbar, KR [1 ]
机构
[1] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA
关键词
D O I
10.1039/b418698b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The step-wise assembly of the high nuclearity cluster, {[ Ni-II(H2O)(5)] (6)[Co-III (tmphen)(2)](3)[Fe-II(CN)(6)](2)}(13+), is achieved by treating {[Co(tmphen)(2)](3)[Fe(CN) (6)](2)} with six equivalents of Ni(ClO4)(2) in aqueous MeOH.
引用
收藏
页码:2451 / 2453
页数:3
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