Highly selective epoxidation of alkenes and styrenes with H2O2 and manganese complexes of the cyclic triamine 1,4,7-trimethyl-1,4,7-triazacyclononane

被引：113

作者：

DeVos, D ^{[1
]}

Bein, T ^{[1
]}

机构：

[1] PURDUE UNIV,DEPT CHEM,W LAFAYETTE,IN 47907

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 08期

关键词：

D O I：

10.1039/cc9960000917

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In acetone and at subambient temperatures, manganese complexes of 1,4,7-trimethyl-1,4,7-triazacyclononane catalyse the selective oxidation of many alkenes and styrenes to epoxides with an efficient use of H2O2; the regio- and chemo-selectivity resemble those of manganese-porphyrin catalysts.

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页码：917 / 918

页数：2

相关论文

共 13 条

[1] MONOOXYGENASE-LIKE OXIDATION OF HYDROCARBONS BY H2O2 CATALYZED BY MANGANESE PORPHYRINS AND IMIDAZOLE - SELECTION OF THE BEST CATALYTIC-SYSTEM AND NATURE OF THE ACTIVE OXYGEN SPECIES [J].

BATTIONI, P ;

RENAUD, JP ;

BARTOLI, JF ;

REINAARTILES, M ;

FORT, M ;

MANSUY, D .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (25) :8462-8470

[2] MECHANISM AND DYNAMICS IN THE H-3[PW12O40]-CATALYZED SELECTIVE EPOXIDATION OF TERMINAL OLEFINS BY H2O2 - FORMATION, REACTIVITY, AND STABILITY OF (PO4[WO(O-2)(2)](4))(3-) [J].

DUNCAN, DC ;

CHAMBERS, RC ;

HECHT, E ;

HILL, CL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (02) :681-691

[3] EPOXIDATION REACTIONS CATALYZED BY IRON PORPHYRINS - OXYGEN-TRANSFER FROM IODOSYLBENZENE [J].

GROVES, JT ;

NEMO, TE .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (18) :5786-5791

[4] EFFICIENT MANGANESE CATALYSTS FOR LOW-TEMPERATURE BLEACHING [J].

HAGE, R ;

IBURG, JE ;

KERSCHNER, J ;

KOEK, JH ;

LEMPERS, ELM ;

MARTENS, RJ ;

RACHERLA, US ;

RUSSELL, SW ;

SWARTHOFF, T ;

VANVLIET, MRP ;

WARNAAR, JB ;

VANDERWOLF, L ;

KRIJNEN, B .

NATURE, 1994, 369 (6482) :637-639

[5]

KINNEARY JF, 1988, J AM CHEM SOC, V110, P6142

[6] SODIUM-HYPOCHLORITE - A CONVENIENT OXYGEN SOURCE FOR OLEFIN EPOXIDATION CATALYZED BY (PORPHYRINATO)MANGANESE COMPLEXES [J].

MEUNIER, B ;

GUILMET, E ;

DECARVALHO, ME ;

POILBLANC, R .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1984, 106 (22) :6668-6676

[7] IRON CYCLAM COMPLEXES AS CATALYSTS FOR THE EPOXIDATION OF OLEFINS BY 30-PERCENT AQUEOUS HYDROGEN-PEROXIDE IN ACETONITRILE AND METHANOL [J].

NAM, WW ;

HO, R ;

VALENTINE, JS .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (18) :7052-7054

[8] THE MANGANESE-CONTAINING POLYOXOMETALATE, [WZNMN2II(ZNW9O34)(2)](12-), AS A REMARKABLY EFFECTIVE CATALYST FOR HYDROGEN-PEROXIDE MEDIATED OXIDATIONS [J].

NEUMANN, R ;

GARA, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (18) :5066-5074

[9] ALKYL HYDROPEROXIDE OXIDATION OF ALKANES AND ALKENES WITH A HIGHLY-ACTIVE MN CATALYST [J].

SARNESKI, JE ;

MICHOS, D ;

THORP, HH ;

DIDIUK, M ;

POON, T ;

BLEWITT, J ;

BRUDVIG, GW ;

CRABTREE, RH .

TETRAHEDRON LETTERS, 1991, 32 (09) :1153-1156

[10] EPOXIDATION OF OLEFINS WITH CATIONIC (SALEN)MNIII COMPLEXES - THE MODULATION OF CATALYTIC ACTIVITY BY SUBSTITUENTS [J].

SRINIVASAN, K ;

MICHAUD, P ;

KOCHI, JK .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (09) :2309-2320