Remote asymmetric induction using chiral sulfoxides

被引：6

作者：

Arai, Y ^{[1
]}

机构：

[1] Gifu Pharmaceut Univ, Gifu 5028585, Japan

来源：

JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN | 1998年 / 56卷 / 10期

关键词：

remote asymmetric induction; chiral sulfoxide; Lewis acid; 1,2-reduction; asymmetric cleavage; 1,4-conjugate addition; Diels-Alder reaction; hetero Diels-Alder reaction; 5-membered aromatic heterocycle;

D O I：

10.5059/yukigoseikyokaishi.56.798

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A overview of recent studies on remote asymmetric induction using chiral sulfoxides, with ca. 30 references i.e., a) reductions of sulfinyl ketones, b) C-O bond fission reactions of sulfinyl bicyclic acetals, c) Mukaiyama aldol condensations of sulfinyl aldehydes, and d) hetero Diels-Alder reactions and Diels-Alder reactions of sulfinyl dienophiles, is described. The role of the sulfinyl auxiliary and the Lewis acid, and the stereoselectivities are also analyzed.

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页码：798 / 809

页数：12

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