Metal-centered photoinduced electron transfer reduction of a gold(III) porphyrin cation linked with a zinc porphyrin to produce a long-lived charge-separated state in nonpolar solvents

被引：111

作者：

Fukuzumi, S ^{[1
]}

Ohkubo, K

E, WB

Ou, ZP

Shao, JG

Kadish, KM

Hutchison, JA

Ghiggino, KP

Sintic, PJ

Crossley, MJ

机构：

[1] Osaka Univ, Grad Sch Engn, Dept Mat & Life Sci, CREST,JST, Suita, Osaka 5650871, Japan

[2] Univ Houston, Dept Chem, Houston, TX 77204 USA

[3] Univ Melbourne, Photophys Lab, Sch Chem, Melbourne, Vic 3010, Australia

[4] Univ Sydney, Sch Chem, Sydney, NSW 2006, Australia

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2003年 / 125卷 / 49期

关键词：

D O I：

10.1021/ja037214b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Photoexcitation of an electron donor?acceptor linked dyad containing gold(III) and zinc(II) porphyrins (ZnPQ?AuIIIPQ+) results in electron transfer from the singlet excited state of ZnPQ to the metal center of AuPQ+ to produce the charge-separated state (ZnPQ•+?AuIIPQ) which has a long lifetime (10 μs) in nonpolar solvents such as cyclohexane and toluene. Copyright © 2003 American Chemical Society.

引用

页码：14984 / 14985

页数：2

共 27 条

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