Organic donor/acceptor heterojunction photovoltaic devices based on zinc phthalocyanine and a liquid crystalline perylene diimide

被引:84
作者
Kim, JY
Bard, AJ
机构
[1] Korea Adv Inst Sci & Technol, Dept Chem & Biomol Engn, Taejon 305701, South Korea
[2] Univ Texas, Dept Chem & Biochem, Austin, TX 78712 USA
基金
美国国家科学基金会;
关键词
D O I
10.1016/j.cplett.2003.10.132
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
An organic photovoltaic cell was fabricated, with the configuration ITO/zinc phthalocyanine (ZnPc)/N,N'-diheptyl-3,4,9,10-perylenebiscarboximide (PTCDI-C7) (PTCDI)/Ga:In. PTCDI is a liquid crystal and acts as an electron acceptor organic material while ZnPc corresponds to a donor. The cell performance under illumination was examined with different organic layer thickness. A cell incorporating 25 nm thick organic layers showed a short circuit photocurrent (I-SC) of 1.6 mA/cm(2), an open circuit photovoltage (V-OC) of 0.6 V, and a fill factor (FF) of 0.4 with white Xe light illumination (wavelength greater than or equal to400 nm) with an intensity of 100 mW/cm(2). (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码:11 / 15
页数:5
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