Reduction of dinitrogen to planar bimetallic M2(μ-η2:η2-N2) complexes of Y, Ho, Tm, and Lu using the K/Ln[N(SiMe3)2]3 reduction system

被引：97

作者：

Evans, WJ ^{[1
]}

Lee, DS ^{[1
]}

Ziller, JW ^{[1
]}

机构：

[1] Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 02期

关键词：

D O I：

10.1021/ja036923m

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction of Ln[N(SiMe3)2]3 with K under N2 in THF forms the dinitrogen complexes {[(Me3Si)2N]2(THF)Ln}2(μ-η2:η2-N2) (Ln = Y, Ho, Tm, and Lu) previously available only for lanthanides with highly reducing divalent states, that is, Tm, Dy, and Nd. The Y and Lu complexes are the first diamagnetic complexes of this type. The Ln2N2 moiety is planar, and the 1.268(3) and 1.285(4) Å NN distances in these complexes are consistent with the presence of (N2)2. Copyright © 2004 American Chemical Society.

引用

页码：454 / 455

页数：2

共 36 条

[1] Bochkarev MN, 2001, ANGEW CHEM INT EDIT, V40, P3176, DOI 10.1002/1521-3773(20010903)40:17<3176::AID-ANIE3176>3.0.CO
[2] 2-Y
[3] Synthesis and structure of the first molecular thulium(II) complex: [TmI2(MeOCH(2)CH(2)OMe)(3)]
Bochkarev, MN
Fedushkin, IL
Fagin, AA
Petrovskaya, TV
Ziller, JW
BroomhallDillard, RNR
Evans, WJ
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1997, 36 (1-2): : 133 - 135
[4] LOW COORDINATION NUMBERS IN LANTHANIDE AND ACTINIDE COMPOUNDS .1. PREPARATION AND CHARACTERIZATION OF TRIS[BIS(TRIMETHYLSILYL)-AMIDO]LANTHANIDES
BRADLEY, DC
GHOTRA, JS
HART, FA
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1973, (10): : 1021 - 1027
[5] The fixation and reduction of dinitrogen using lanthanides: praseodymium and neodymium meso-octaethylporphyrinogen-dinitrogen complexes
Campazzi, E
Solari, E
Floriani, C
Scopelliti, R
[J]. CHEMICAL COMMUNICATIONS, 1998, (23) : 2603 - 2604
[6] Synthesis and characterization of organolanthanidocene(III) (Ln = La, Ce, Pr, Nd) complexes containing the 1,4-cyclohexa-2,5-dienyl ligand (benzene 1,4-dianion):: Structures of [K([18]-crown-6)][Ln{η5-C5H3(SiMe3)2-1,3}2(C6H6)] [Cp" = η5-C5H3(SiMe3)2-1,3; Ln = La, Ce, Nd]
Cassani, MC
Gun'ko, YK
Hitchcock, PB
Lappert, MF
Laschi, F
[J]. ORGANOMETALLICS, 1999, 18 (26) : 5539 - 5547
[7] Cassani MC, 1997, CHEM COMMUN, P1563
[8] Cassani MC, 2002, J ORGANOMET CHEM, V647, P71
[9] Tetrametallic divalent samarium cluster hydride and dinitrogen complexes
Dubé, T
Ganesan, M
Conoci, S
Gambarotta, S
Yap, GPA
[J]. ORGANOMETALLICS, 2000, 19 (18) : 3716 - 3721
[10] Edelmann F. T., 1997, SYNTH METHODS ORGANO, V6, P37

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